Enhancing Phosphorus Recovery from Scraped Liquid Dairy Manure Using Process Effluent

Purpose

Our long term goal is to develop a robust phosphorus (P) recovery technology suitable for use on dairy farms of all sizes through an integrated research and extension program for manure nutrient recovery. Enrichment of water bodies by P in agricultural runoff has been and remains the focus of water quality protection. Animal feeding operations (AFOs), regardless of size, especially in sensitive ecosystems and the Chesapeake Bay (Bay) in particular, have been identified as major contributors to water and air pollution. These operations are facing extra scrutiny by state and federal regulation agencies with regards to nutrient management. Although nutrient management plans have not been required for most dairy farms in Virginia, this status is changing rapidly. Nutrient reductions in unregulated small dairies has been identified as part of the strategy to clean up the Bay. Our project focuses manure P management on dairy farms and will particularly benefit dairy farms in Shenandoah Valley, Virginia and Lancaster County, Pennsylvania, where excess P in manure is a huge challenge. The dairies in these localities are predominantly small and are key drivers of local economies. About 1,928 (averaging 60 milking cows per farm) and 321 (averaging 80 cows per farms) facilities are located in Lancaster county and central Shenandoah Valley, respectively (USDA NASS, 2014). If implemented on farms, our project will help remove the excess P and allow the continued use of manure as a fertilizer in areas that may be restricted by the P-based manure application regulations. Also, it will help prevent over application of P, which is a typical result of applying manure to meet crop N needs.

What did we do? 

We use the “designer manures” approach as a guiding philosophy to manure nutrient management. Our working definition of designer manure is “a manure based product with the appropriate balance of N and P fertilizer values that meet specific requirements of different crops”. We conducted lab scale tests using chemical salts of aluminum, iron and calcium to identify the most effective chemical and method to recover manure P in scraped dairy manure. In the state of Virginia, the total solids (TS) content of manure from most dairies ranges between 4 to 6%. This TS range requires dilution to bring the levels to about 2% for chemicals to precipitate manure effectively. Dilution was achieved using supernate (process liquid) to dilute 4% TS dairy manure to recover P. Our lab studies have shown aluminum to be the best chemical.

What have we learned? 

Some of our results are shown in Figure 1 for aluminum chloride and aluminum sulfate. Using 600 mg Al/L we are able to remove over 95% of the total P (supernate liquid). No significant accumulation of metal salts or solids was observed in the supernate even after eight passes. Iron based chemicals produced too much foam and the resulting sludge with very poor settling characteristics. This project has the potential of concentrating manure P into small volumes and quantities that can be transported off farm and positively impact the nutrient management practices on farms.

Figure 1 total solids

figure_1.pdf

Future Plans

Chemical precipitation has not been widely adopted for agricultural purposes because (1) they require a very dilute manure stream and require some sort of automated application, (2) cost of the chemicals may be high and not enough expertise on the farm to handle chemicals, and (3) solids and nutrients precipitated still need to be managed appropriately. We are actively seeking funds to install a demonstration unit on a farm where producers and other interested parties can come learn how to overcome these challenges and experience the technology.

Authors

Jactone A. Ogejo, Assoc. Prof arogo@vt.edu

Sampath Karunarathne, Graduate Student; Madonna Yoder, Research Assistant

Additional information

DeBusk, J.A., J.A. Ogejo, K.F. Knowlton, N.G. Love. 2008. Chemical phosphorus removal for separated flushed dairy manure. Applied Engineering in Agriculture 24(4): 499-506

The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2015. Title of presentation. Waste to Worth: Spreading Science and Solutions. Seattle, WA. March 31-April 3, 2015. URL of this page. Accessed on: today’s date.

Manure Production and Characteristics

Manure is an inevitable byproduct of livestock and poultry production. Manure is a valuable material that can be used as a source of organic matter and fertilizer for crop and pasture production. Manure can also be used as source of energy on the farm through anaerobic digestion to produce biomethane or thermochemical process (such as pyrolysis, gasification, or combustion) to produce heat or electricity. Some of the by-products of energy production can be further processed to produce value added chemicals.

Quantity of Manure Produced

Typically, manure includes excreted material from the animal (feces and urine), used bedding, as well as wasted feed, water (drinking and wash), hair, and soil. The quantity of manure produced depend on several factors including:

  • animal type (ruminant or non-ruminant),
  • diet (forage-based or grain-based),
  • animal age (which can influence the amount of feed consumed),
  • animal environment,
  • and animal productivity as well as other factors.

Composition of Manure

The chemical characteristics of manure primarily depend upon the chemical composition of the feed given to the animal. The animal metabolizes the feed to provide itself with energy and produce new body tissues and products. The waste products of metabolism are largely collected in urine and passed out with the feces (which may contain unused feed).

Nutrient requirements by animals vary with animal type and stage of production. Usually, when the animal’s protein requirements decrease, the concentration of protein in the diet can also be decreased, thereby decreasing the concentrations of nitrogen excreted as a percent of body weight. Similarly, increased levels of minerals fed (e.g. copper, phosphorus, sodium, potassium) increase the level of those nutrients in the manure. It is recommended that manure analysis be done regularly especially if diet formulation and major changes in management of the livestock occurs.

Determining Manure Production and Composition

Manure quantities and characteristics can be estimated on an:

  1. as-excreted basis or as
  2. recoverable manure nutrients (the quantity of manure nutrients available for land application or utilization for other purposes).

The nutrient content of manure is influenced by feed intake (which influences the nutrients excreted), manure storage and management choices (which influences the recovery of nutrients), and water additions/evaporation (which influences the concentration of nutrients).

As-Excreted Basis

There are tabulated values that can be used to estimate the amount of manure an animal produces. The American Society of Agricultural and Biological Engineers (ASABE) has prepared a standard (D384.2) that lists the average quantities of manure and their characteristics. Excreted values are provided in Table 1 and Table 2. These average estimates of manure excreted become obsolete due to changes in animal genetics, feeding program strategies, and available feeds. Table 1 and 2 are representative of typical characteristics in 2002.

Although sampling and the use of tabulated estimates are the most common methods of estimating manure nutrients, ASABE D384.2 provide equations for predicting nutrient excretion (primarily nitrogen and phosphorus), dry matter, and (depending upon species) other potential characteristics have been assembled for beef, dairy, swine, horses, and poultry. Software (listed at the bottom of this page) can simplify the use of these equations.

If you want to calculate quantity of manure produced by your animals based on these equations, here are some guidelines to use to decide when it is appropriate to use the equations to calculate manure excretions:

  • When you want to develop a comprehensive nutrient management plans specific to your animal feeding operation (AFO).
  • When you have farm-specific data for your feeding program and animal performance.
  • When feed intake, feed nutrient concentration, feed digestibility, or animal performance varies from the assumptions used to estimate the typical values in Table 1 and Table 2.
  • When industry trends have changed from the assumptions used in Table 1.

Otherwise, use the typical values found in Table 1 and Table 2 for the following situations:

  • When planning estimates are being made on a scale larger than a single farm (e.g. county or regional estimate of nutrient excretion).
  • When a rough approximation is needed for farm planning.
  • When farm-specific information of animal performance and feed intake is not available.

Caution: When using the typical as-excreted manure production and characteristics presented in Table 1 and Table 2, the user should recognize that the reported typical values may become obsolete with time due to changes in animal genetics, feeding programs, alternative feeding technologies, and available feeds. In addition, users should also recognize that under current conditions, excretion of nutrients and other related characteristics will vary for individual situations from the currently listed values due to variations in animal feed nutrient intake, animal performance, and individual farm management.

Bedding

Bedding is sometimes included in the manure. To estimate the amount of bedding used, weigh the bedding added to each pen per week and multiply the number of pens and the weeks between cleaning. Estimate the total weight of bedding and manure by adding the amount of manure produced using Table 1 or Table 2 or calculated using equations to the amount of bedding; subtract any liquid drained off i.r. not absorbed by the bedding (neglect drainage if well bedded).

Total Weight = manure weight + bedding weight

To estimate the volume of the manure and bedding, add manure production volume to 50% of the bedding volume. The volume of the bedding is usually reduced by half during use.

Total Volume = manure volume + (bedding volume/2)

As-Removed Manure Production and Characteristics

Many physical, chemical, and biological processes can alter manure characteristics from its original as-excreted form. The as-removed manure production characteristics values are reported in Table 3. These values represent typical values based on available data sources. These estimates may be helpful but have very high variability. The values may be helpful for an individual farm’s long-term planning prior to any samples being available and for planning estimates addressing regional issues. Whenever possible, site-specific samples or other more localized estimates should be used instead of the national tabular estimates. Permitted Concentrated Animal Feeding Operations (CAFOs) are required to annually report recovered manure for their individual farm. Use the tabulated values for planning purposes until site-specific values are available.

Manure Handling Characteristics

The handling characteristics of manure vary depending primarily on the solids content (Figure 20-1). Manure is usually classified as liquid, slurry, semi-solid, or solid depending on the total solids content of the manure. The boundary between handling classifications is not fixed but varies with specific composition.

Manure can be classified according to the dry matter content as liquid, slurry, semi-solid and solid.

  • Liquid manure contains up to 4% solids content and can be handled with irrigation equipment. Liquid manure with this kind of solids content can be obtained by removing larger solids from the manure through some form of solids separation, or adding dilution water. Lagoon treatment systems usually have less than 1% solids if designed and operated properly. Overloaded lagoons can reach up to 2% solids.
  • Slurry manure contains 4% to 10% solids and may require special pumps for handling. *Semi-solid manure contains between 10 and 20% solids. The manure is too thick to pump.
  • Solid manure contains 20% solids content or more. This manure can be stacked or be picked up with a fork or bucket loader.

 

Figure 1. Relative handling characteristics of different types of manure for various animal species (Source: MWPS-18 Section 1, 2004). cc2.5 Jactone Arogo Ogejo

 

 

Software

The spreadsheet, Feed Nutrient Management Planning Economics (FNMP$) is a comprehensive program connecting feed ration characteristics, manure storage type and cropping systems impact on the value of manure as a fertilizer. The spreadsheet provides a straightforward approach for estimating manure excretion based on the ASABE equations standard described above. FNMP$ estimates:

  1. manure nutrients
  2. land requirements
  3. labor and equipment application time, and
  4. costs and value for land application.

This is a spreadsheet-based program.

References

  • MWPS. 2004. Manure Characteristics.MWPS-18 Section 1. MidWest Plan Service, Ames. IA
  • ASABE. 2005. Manure production and characteristics. ASABE Standard D384.2. American Society of Agricultural and Biological Engineers. St. Joseph, MI.

Author: Jactone Arogo Ogejo, Virginia Tech