Volatile Organic Compound (VOC) Emissions from Beef Feedlot Pen Surface as Affected by Within Pen Location, Moisture, and Temperature

Purpose

Determine the effects of moisture, temperature and within pen location on odorous emissions from pen surfaces generated from cattle fed a diet containing 30% wet distillers grain plus soluble (WDGS). This work is focused on developing precision practices for mitigating odor.

What did we do?

A laboratory study was conducted to determine effects of pen location, moisture, and temperature on emissions of volatile organic compounds (VOC). Feedlot surface material (FSM) was obtained from pens where cattle were fed a diet containing 30% wet distillers grain plus soluble (WDGS). The FSM were collected from the bunk, drainage, and mound areas within three feedlot pens. The FSM were mixed with water to represent dry, wet, or saturated conditions and then incubated at temperatures of 5, 15, 25 and 35ºC. A wind tunnel and TD GC/MS were used to quantify emissions of eight volatile fatty acids (VFA), five aromatics and two volatile sulfur compounds (VSC).

graph showing experiment results. Contribution to total odor activity value (OAV) for each feedlot pen location, moisture condition, and temperature. All within treatment odor activity values sum to 100%.What have we learned?

Evaluation of emissions as affected by the specified environmental conditions was performed on individual compounds which were normalized using an odor activity value (OAV). When the odor compounds were normalized with respect to their activity value, many of the measured compounds contributed minimally to the overall odor activity. Approximately 10% of the OAV was contributed by three VFAs and one aromatic (4-methylphenol) compound. The VSC contributed the most with 87.3% of the total OAV.

More than half of the OAV occurred at the base of the mound with the bunk and drainage contributing approximately equally to the remainder. The frequent wetting and drying cycles occurring near the base of the mound may contribute to a more diverse microbial population when compared with the chronically wet to saturated conditions existing behind the feed bunk.

The addition of water significantly increased the OAV. Approximately 92% of the OAV was accounted for by wet and saturated conditions. In general, the addition of water decreased emissions of VFA and aromatics, and increased the emission of sulfides. Two possible causes were offered. First, the greater solubility of the VFA and aromatics allowed them to be retained in the solution fraction of the FSM and not be emitted. Second, the addition of water results in an anaerobic environment and reducing conditions, which are conducive to production of VSC.

Temperature significantly affected OAV with over 60% of the total OAV occurring at 35ºC. The 35ºC temperature increased each odor compounds with the impact being the greatest for VSCs. It appears from this study, odor emissions are greatest during warm (i.e. > 25ºC) wet periods and from specific location within the pen.

Future Plans

Understanding the spatial variability of odor emission is important in the development of cost-effective management practices. Based on the results from this investigation, field-scale studies will be conducted to develop precision odor mitigation practices.

Authors

Bryan L. Woodbury, Agricultural Engineer, USDA-ARS, U.S. Meat Animal Research Center, Clay Center, NE bryan.woodbury@ars.usda.gov

John E. Gilley, Agr. Eng, USDA-ARS. David B. Parker, Prof., Life, Earth and Environ. Sci., West Texas A&M University. David B. Marx, Prof, Statistics, Univ. of NE. Roger A. Eigenberg, Agr. Eng., USDA-ARS, U.S.

Additional information

http://www.ars.usda.gov/Main/docs.htm?docid=14337

https://www.agupdate.com/todaysproducer/news/local/with-feedlot-manure-it-pays-to-be-precise/article_015b6db8-a234-582d-8c0e-04b99cf0f730.html

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