pig manure – Livestock and Poultry Environmental Learning Community

March 5, 2019March 5, 2021

USDA-NRCS and the National Air Quality Site Assessment Tool (NAQSAT) for Livestock and Poultry Operations

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Purpose

The National Air Quality Site Assessment Tool (NAQSAT) was developed as a first-of-its-kind tool to help producers and their advisors assess the impact of management on air emissions from livestock and poultry operations and identify areas for potential improvement related to those air emissions.

What did we do?

In 2007, several land-grant universities, with leadership from Michigan State University, began developing NAQSAT under a USDA-NRCS Conservation Innovation Grant (CIG). The initial tool included beef, dairy, swine, and poultry operations. A subsequent CIG project, with leadership from Colorado State University, made several enhancements to the tool, including adding horses to the species list. In 2015, USDA-NRCS officially adopted NAQSAT as an approved tool for evaluating air quality resource concerns at livestock and poultry operations. USDA-NRCS also contracted with Florida A&M University in 2015 to provide several regional training workshops on NAQSAT to NRCS employees. Six training workshops have been completed to date (Raleigh, NC; Modesto, CA; Elizabethtown, PA; Lincoln, NE; Richmond, VA; and Yakima, WA) with assistance from multiple NAQSAT development partners. Additionally, USDA-NRCS revised its comprehensive nutrient management plan (CNMP) policy in October 2015 to make the evaluation of air quality resource concerns mandatory as part of CNMP development.

What have we learned?

NAQSAT has proven to be a useful tool for bench-marking the air emissions impacts of current management on confinement-based livestock and poultry operations. In the training sessions, students have been able to complete NAQSAT runs on-site with the producer or producer representative via tablet or smartphone technologies. Further classroom discussion has helped to better understand the questions and answers and how the NAQSAT results can feed into the USDA-NRCS conservation planning process. Several needed enhancements and upgrades to the tool have been identified in order to more closely align the output of the tool to USDA-NRCS conservation planning needs. NAQSAT has also proven to be useful for evaluating the air quality resource concern status of an operation in relation to the CNMP development process.

Future Plans

It is anticipated that the identified needed enhancements and upgrades will be completed as funding for further NAQSAT development becomes available. Additionally, as use of NAQSAT by USDA-NRCS and our conservation planning and CNMP development partners expands, additional training and experience-building opportunities will be needed. The NAQSAT development team has great geographic coverage to assist in these additional opportunities.

Corresponding author, title, and affiliation

Greg Zwicke, Air Quality Engineer – Air Quality and Atmospheric Change Team, USDA-NRCS

Corresponding author email

greg.zwicke@ftc.usda.gov

Other authors

Greg Johnson, Air Quality and Atmospheric Change Team Leader, USDA-NRCS; Jeff Porter, Animal Nutrient and Manure Management Team Leader, USDA-NRCS; Sandy Means, Agricultural Engineer – Animal Nutrient and Manure Management Team, USDA-NRCS

Additional information

naqsat.tamu.edu

https://lpelc.org/naqsat-for-swine-and-poultry

https://lpelc.org/naqsat-for-beef-and-dairy/

Acknowledgements

C.E. Meadows Endowment, Michigan State University

Colorado Livestock Association

Colorado State University

Florida A&M University

Iowa Turkey Federation

Iowa Pork Producers

Iowa Pork Industry Center

Iowa State University

Iowa State University Experiment Station

Kansas State University

Michigan Milk Producers Association

Michigan Pork Producers Association

Michigan State University

Michigan State University Extension

National Pork Board

Nebraska Environmental Trust

Oregon State University

Penn State University

Purdue University

Texas A&M University

University of California, Davis

University of Georgia

University of Georgia Department of Poultry Science

University of Idaho

University of Maryland

University of Maryland Department of Animal and Avian Sciences

University of Minnesota

University of Missouri

University of Nebraska

USDA-ARS

Virginia Tech University

Washington State University

Western United Dairymen

Whatcom County (WA) Conservation District

The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2017. Title of presentation. Waste to Worth: Spreading Science and Solutions. Cary, NC. April 18-21, 2017. URL of this page. Accessed on: today’s date.

March 5, 2019March 19, 2019

Nitrogen and Phosphorus Cycling Efficiency in US Food Supply Chains – A National Mass-Balance Approach

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Purpose

Assessing and improving the sustainability of livestock production systems is essential to secure future food production. Crop-livestock production systems continue to impact nitrogen (N) and phosphorus (P) cycles with repercussions for human health (e.g. secondary particle formation due to ammonia emission and drinking water contamination by nitrate) and the environment (e.g. eutrophication of lakes and coastal waters and exacerbation of hypoxic zones). Additionally, P is a limited resource, and sustaining an adequate P supply is a major emerging challenge. To develop strategies for a more sustainable use of N and P, it is essential to have a quantitative understanding of the flows and stocks of N and P within the society. In this study, we developed detailed national N and P budgets to assess nutrient cycling efficiency in US (livestock) food supply chains, to identify hotspots of nutrient loss and to indicate opportunities for improvement!

What did we do?

1. National nutrient mass-balance

A mass-balance framework was developed to quantify nutrient flows within the US. In this framework, the national US system is represented by 9 major sectors are relevant in terms of nutrient flows: mining (relevant for P only), industrial production, agriculture, food & feed processing industry, retail, households and other consumers, energy and transport, humans, and waste treatment. These sectors can exist of several sub-sectors. For example, the agricultural sector consists of several secondary sub-systems including pasture, agricultural soil, livestock and manure management (WMS – waste management system).

Different livestock categories can have distinct environmental impacts and nutrient use efficiencies (e.g. (Hou et al. 2016), (Eshel et al. 2014), (Herrero et al. 2013)), we therefore distinguish six livestock categories (dairy cattle, beef cattle, poultry (meat), poultry (layers), sheep, hogs) and

their associated food commodities (dairy products, beef from dairy cattle, beef, poultry, eggs, lamb, pork).

For each sub-system, we identify and quantify major flows to and from this compartment. All flows are expressed in a common unit, i.e. metric kiloton N per year (kt N/yr) for nitrogen and metric kiloton P per year (kt P/yr) for phosphorus. Quantified flows include nutrient related emissions to the environment and waste flows.

At present, the waste sectors and environmental compartment are outside the system boundaries, that is, we quantify flows to these compartments, but we do not attempt to balance these sectors. We do, however, keep track of the exact chemical species (e.g. emission of N2O-N to air instead of N to air) emitted as far as possible. The municipal waste treatment (MSW) and municipal waste water treatment (WWTP) are treated in more detail: major flows from and to these compartments are quantified. These sub-sectors are treated in more detail because of their role in nutrient recycling through e.g. sewage sludge application on agricultural soils.

Data were collected in priority from national statistics (e.g. USDA NASS for livestock population) and peer-reviewed literature, and were supplemented with information from industrial reports and extension files if needed. If available, data were collected for the years 2009 to 2012 and averaged, when unavailable, we collected data for the closest year.

2. Scenario analysis

In the scenario analysis, we test the opportunity for dairy livestock production systems to contribute to a more efficient nutrient use through anaerobic co-digestion of dairy manure and organic food waste. Recently, Informa Economics assessed the national

market potential of anaerobic digester products for the dairy industry (Informa Economics 2013). Next to a reduction in greenhouse gas emissions, anaerobic co-digestion of dairy manure and organic food waste can contribute to improve nutrient cycling efficiency (Informa Economics 2013). Dairy manure contains high levels of nitrogen and phosphorus, which can be used as a natural crop fertilizer, if recuperated from manure. Presently, non-farm organic substrates such as food waste are typically disposed of in landfills, which causes greenhouse gas (GHG) emissions and also results in a permanent removal of valuable nutrients from the food supply chain (Informa Economics 2013). By anaerobic co-digestion, a part of the nutrien! ts contai ned in dairy manure and food waste can be recovered. These nutrients can be used to fertilize crops and substitute synthetic fertilizer application. In the scenario analysis, we test to what extent anaerobic co-digestion of dairy manure and food waste can contribute to improve nutrient cycling efficiency, particularly by substituting synthetic fertilizers. We develop the scenario based on data provided in the InformaEconomics report.

What have we learned?

In general, our results show that livestock production is the least efficient part of the total food supply chain with large losses associated with manure management and manure and fertilizer application to crops. In absolute terms, the contribution of the household stage to total and N and P losses from the system is small, approximately 5 and 7% for N and P, respectively. However, households ‘waste’ a relatively large percentage of purchased products, (e.g. 16% and 18% of N and P in dairy products end up as food waste), which presents an opportunity for improvement. A scenario was developed to test to what extent anaerobic co-digestion of dairy manure and food waste can contribute to improving nutrient cycling efficiency on a national scale. Results suggest that 22% and 63% of N and P applied as synthetic fertilizer could potentially be avoided in dairy food supply chains by large scale implementation of anaerobic co-digestion o! f manure and food waste.

Future Plans

Future research plans include a further development of scenarios that are known to reduce nutrient losses at the farm scale and to assess the impact of these scenarios on national nutrient flows and losses.

Corresponding author, title, and affiliation

Karin Veltman, PhD, University of Michigan, Ann Arbor

Corresponding author email

veltmank@umich.edu

Other authors

Carolyn Mattick, Phd, Olivier Jolliet, Prof., Andrew Henderson, PhD.

Additional information

Additional information can be obtained from the corresponding author: Karin Veltman, veltmank@umich.edu

Acknowledgements

The authors wish to thank Ying Wang for her scientific support, particularly for her contribution in developing the anaerobic co-digestion scenario.

This work was financially supported by the US Dairy Research Institute.

March 5, 2019March 20, 2019

Early Stage Economic Modeling of Gas-permeable Membrane Technology Applied to Swine Manure after Anaerobic Digestion

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Purpose

The objective of this study was to conduct cost versus design analysis for a gas-permeable membrane system using data from a small pilot scale experiment and projection of cost versus design to farm scale.

What did we do?

This reported work includes two major steps. First, the design of a small pilot scale batch gas-permeable membrane system was scaled to process effluent volumes from a commercial pig farm. The scaling design maintained critical process operating parameters of the experimental membrane system and introduced assumed features to characterize effluent flows from a working pig farm with an anaerobic digester. The scaled up design was characterized in a spreadsheet model. The second step was economic analysis of the scaled-up model of the membrane system. The objective of the economic analysis was to create information to guide subsequent experiments towards commercial development of the technology. The economic analysis was performed by introducing market prices for components, inputs, and products and then calculating effects on costs and on performance of changes in design parameters.

What have we learned?

First, baseline costs and revenues were calculated for the scaled up experimental design. The commercial scale design of a modular gas-permeable membrane system was modeled to treat 6 days accumulation of digester effluent at 16,300 gallons per day resulting in a batch capacity of 97,800 gallons. The modeled large scale system is 19,485 times the capacity of the 5.02 gallon experimental pilot system. The installation cost of the commercial scale system was estimated to be $903,333 for a system treating 97,800 gallon batches over a 6 day period.

At $1/linear ft. and 7.9 ft./gallon of batch capacity, membrane material makes up 86% of the estimated installation cost. Other installation costs include PVC pipes, pumps, aerators, tanks, and other parts and equipment used to assemble the system, as well as water to dilute the concentrated acid prior to initiating circulation. The annual operating cost of the system includes concentrated sulfuric acid consumed in the process. Using limited experimental data on this point, we assume a rate of 0.009 gallons (0.133 pounds) of acid per gallon of digester effluent treated. At a price of $1.11 per gallon ($0.073/lb) of acid, acid cost per gallon of effluent treated is $0.010. Other operating costs include electric power, labor, and repairs and maintenance of the membrane and other parts of the system estimated at 2% of investment cost for non-moving parts and 6% of investment for moving parts. Potential annual revenue from the system includes the value of ammonium sulfate produced. Over the 6 day treatment period, if 85% of the TAN-N in the digester effluent is removed by the process, and if 100% of the TAN-N removed is recovered as ammonium sulfate, and given the TAN-N concentration in digester effluent was 0.012 pounds per gallon (1401 mg/l), then 0.01 pounds of TAN-N are captured per gallon of effluent treated. At an ammonium sulfate fertilizer price of $588/ton or $0.294/pound and ammonium sulfate production of 0.047 pounds (0.01 pounds TAN-N equivalent), potential revenue is $0.014 per gallon of effluent treated. No price is attached here for the elimination of internal and external costs associated with potential release to the environment of 0.01 pounds TAN-N per gallon of digester effluent or 59,073 pounds TAN-N per year from the system modeled here.

Several findings and questions, reported here, are relevant to next steps in experimental evaluation and commercial development of this technology.

1. Membrane price and/or performance can be improved to substantially reduce installation cost. Membrane material makes up 86% of the current estimated installation cost. Each 10% reduction in the product of membrane price and length of membrane tube required per gallon capacity reduces estimated installation cost per gallon capacity by 8.6%.

2. The longevity and maintenance requirements of the membrane in this system were not examined in the experiment. Installation cost recovery per gallon of effluent decreases at a declining rate with longevity. For example, Cost Recovery Factors (percentage of initial investment charged as an annual cost) at 6% annual interest rate vary with economic life of the investment as follows: 1 year life CRF = 106%, 5 year life CRF = 24%, 10 year life CRF = 14% . Repair costs are often estimated as 2% of initial investment in non-moving parts. In the case of the membrane, annual repair and maintenance costs may increase with increased longevity. Longevity and maintenance requirements of membranes are important factors in determining total cost per gallon treated.

3. Based on experimental performance data (TAN removal in Table 1) and projected installation cost for various design treatment periods ( HRT = 2, 3, 4, 5, or 6 days), installation cost per unit mass of TAN removal decreases and then increases with the length of treatment period. The minimum occurs at HRT = 4 days when 68% reduction of TAN-N in the effluent has been achieved.

4. Cost of acid relative to TAN removal from the effluent and relative to fertilizer value of ammonium sulfate produced per gallon of effluent treated are important to operating cost of the membrane system. These coefficients were beyond the scope of the experiment although some pertinent data were generated. Questions are raised about the fate of acid in circulation. What fraction of acid remains in circulation after a batch is completed? What fraction of acid reacts with other constituents of the effluent to create other products in the circulating acid solution? What fraction of acid escapes through the membrane into the effluent? Increased efficiency of TAN removal from the effluent per unit of acid consumed will reduce the cost per unit TAN removed. Increased efficiency of converting acid to ammonium sulfate will reduce the net cost of acid per gallon treated.

5. Several operating parameters that remain to be explored affect costs and revenues per unit of effluent treated. Among those are parameters that potentially affect TAN movement through the membrane such as: a) pH of the effluent and pH of the acid solution in circulation, b) velocity of liquids on both sides of the membrane, and c) surface area of the membrane per volume of liquids; effluent and acid solution, in the reactor. Similarly, the most profitable or cost effective method of raising pH of the digester effluent remains to be determined, as it was beyond the scope of the current study. Aeration was used in this experiment and in the cost modeling. Aeration may or may not be the optimum method of raising pH and the optimum is contingent on relative prices of alternatives as well as their effect on overall system performance. Optimization of design to maximize profit or minimize cost requires knowledge of these performance response functions and associated cost functions.

6. Management of ammonium sulfate is a question to be addressed in future development of this technology. Questions that arise include: a) how does ammonium sulfate concentration in the acid solution affect rates of TAN removal and additional ammonia sulfate production, b) how can ammonium sulfate be removed from, or further concentrated in, the acid solution, c) can the acid solution containing ammonium sulfate be used without further modification and in which processes, d) what are possible uses for the acid solution after removal of ammonium sulfate, e) what are the possible uses for the effluent after removal of some TAN, and f) what are the costs and revenues associated with each of the alternatives. Answers to these questions are important to designing the membrane system and associated logistics and markets for used acid solution and ammonium sulfate. The realized value of ammonium sulfate and the cost (and revenue) of used acid solution are derived from optimization of this p art of the system.

7. LCA work on various configurations and operating parameters of the membrane system remains to be done. Concurrent with measurement of performance response functions for various parts of the membrane system, LCA work will quantify associated use of resources and emissions to the environment. Revenues may arise where external benefits are created and markets for those benefits exist. Where revenues are not available, marginal costs per unit of emission reduction or resource extraction reduction can be calculated to enable optimization of design across both profit and external factors.

Future Plans

A series of subsequent experiments and analyses are suggested in the previous section. Suggested work is aimed at improving knowledge of performance response to marginal changes in operating parameters and improving knowledge of the performance of various membranes. Profit maximization, cost minimization, and design optimization across both financial and external criteria require knowledge of performance response functions over a substantial number of variables. The economic analysis presented here addresses the challenge of projecting commercial scale costs and returns with data from an early stage experimental small pilot; and illustrates use of such preliminary costs and returns projections to inform subsequent experimentation and development of the technology. We will continue to refine this economic approach and describe it in future publications.

Corresponding author, title, and affiliation

Kelly Zering, Professor, Agricultural and Resource Economics, North Carolina State University

Corresponding author email

kzering@ncsu.edu

Other authors

Yijia Zhao, Graduate Student at BAE, NCSU; Shannon Banner, Graduate Student at BAE, NCSU; Mark Rice, Extension Specialist at BAE, NCSU; John Classen, Associate Professor and Director of Graduate Programs at BAE, NCSU

Acknowledgements

This project was supported by NRCS CIG Award 69-3A75-12-183.

March 5, 2019March 20, 2019

Recovery of Proteins and Phosphorus from Manure

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*Purpose

The recovery of phosphorus and proteins from manure could be advantageous to both offset costs and to improve and lessen the environmental impacts of manure storage and treatment. Phosphorous in manure can contaminate rivers, lakes, and bays through runoff, if applied onto cropland at excessive rates. Thus, recovering phosphorous from manure can not only help reduce phosphorus loss in runoff, but also reduces the use of commercial fertilizer based upon phosphate rock. Phosphorus mines have limited reserves and viable alternatives for replacing rock phosphate as fertilizer do not exist. Protein is a natural resource used in a wide range of commercial applications from pharmaceuticals to dietary supplements, foods, feeds, and industrial applications.

What Did We Do?

A new method for simultaneous extraction of proteins and phosphorus from biological materials has been developed and is presented. The experiments used swine manure solids fraction after solids-liquid separation. From raw manure, wet solids are dissolved in acidic solution and then treated with a basic solution so phosphorus will precipitate and be reclaimed. The proteins in the washed solids can be extracted and concentrated with ultrafiltration and flocculation.

Test tubes filled with proteins from manure

What Have We Learned?

On a dry-weight basis, it was found that the separated manure solids contained 15.2-17.4% proteins and 3.0% phosphorus. Quantitative extraction of phosphorus and proteins from manures was possible with this new system. The phosphorus was first separated from the solids in a soluble extract, then the proteins were separated from the solids and solubilized with an alkali solvent. Both phosphorus and protein recovery were enhanced about 19 and 22%, respectively, with the inclusion of a rinse after the washing. The recovered phosphorus solids had 20.4% phosphates (P2O5). The protein extract was concentrated using ultrafiltration (UF) and lyophilization to obtain a protein solids concentrate. UF of 5 and 10 kDa captured all the proteins, but 30 kDa resulted in 22% loss. The protein solids were converted into amino-acids using acid hydrolysis. Further, the system was proved effective in extracting phosphorus and proteins from other biological materials, such as algae or crops. The recovered proteins could be used for production of amino acids and the recovered phosphorus could be used as a recycled material that replaces commercial phosphate fertilizers. This could be a potential new revenue stream from wastes.

Future Plans

Further research will be conducted to reduce process costs and separate the amino acids.

Corresponding author (name, title, affiliation)

Matias Vanotti, USDA-ARS

Corresponding author email address

matias.vanotti@ars.usda.gov

Other Authors

A.A. Szogi, P.W. Brigman

Additional Information

Vanotti, M.B. and Szogi, A.A. (2016). Extraction of amino acids and phosphorus from biological materials. US Patent Application SN 15/350,283. U.S. Patent & Trademark Office.

USDA-ARS Office of Technology Transfer, Invention Docket No: 080.15, Contact: thomas.valco@ars.usda.gov

Acknowledgements

This research is part of USDA-ARS Project 6082-12630-001-00D “Improvement of Soil Management Practices and Manure Treatment/Handling Systems of the Southern Coastal Plains.” We acknowledge the field and laboratory assistance of William Brigman and Chris Brown, USDA-ARS, Florence, SC. Support by The Kaiteki Institute, Mitsubishi Chemical Holdings Group through ARS Cooperative Agreement 58-6082-5-006-F is acknowledged.

March 5, 2019March 20, 2019

Renewable Energy Set-asides Push Biogas to Pipeline

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Purpose

Deriving the most value from the harvesting of organic wastes, particularly waste produced through farming operations, can be quite challenging. This paper describes an approach to overcome the challenges of realizing the best value from harvested farming wastes through aggregation. Included in this description is an overview of the first swine waste-to-energy project in North Carolina based on aggregation of the value stream rather than aggregation of the feedstock, or manure. Also included in the description are an overview of the challenges encountered, approaches to overcome these challenges, and the solutions developed for this breakthrough approach that will foster further development of successful ventures to maximize the value derived from recycled farming wastes.

What did we do?

Increasingly, our civilization is turning to bioenergy sources as an environmentally-friendly, sustainable alternative to harvesting long-buried fossil fuel sources to supply our energy needs. As the land that farmers have cultivated for years becomes encroached more and more by non-farming land uses, society seeks innovations to address its concerns for our future food needs produced in a manner that addresses environmental concerns associated with modern food production, including nutrient recovery, water conservation and reuse, and controlling odors and emissions from agricultural wastes and manures. Collectively, these innovations have been described as ‘sustainable farming’ approaches.

North Carolina is a significant agricultural producer, and as such, a large producer of agricultural wastes. This state also became the first state in the Southeast to adopt a Renewable Energy Portfolio Standard, and is the only state in the U.S. to require a certain percentage of that renewable energy must be generated from agriculture waste recovery, with specific targets for swine and poultry waste. Naturally, the plentiful resources coupled with a regulatory driver for renewable energy worked together to create attention and efforts toward cost-effective and efficient means of supplying our energy needs through organic waste recovery, or bioenergy approaches.

We are only beginning to see a surge in commercial development for the recovery of additional value stream from the waste, such as through the recovery of nutrients, enzymes, and monetized environmental attributes associated with pollution abatement. While many forward-thinking farmers have learned that their waste is valuable for supplying renewable energy, it has been unfortunately difficult for an individual farmer to implement and manage advanced value recovery systems primarily due to costs of scale. Rather, it seems, success may be easier achieved through the aggregation of these products from several farms and through the collaborative efforts of project developers, product offtakers, and policy. A shining example of such aggregation and collaboration can be observed from the Optima-KV swine waste to pipeline renewable gas project, located in eastern North Carolina in an area of dense swine farm population.

The Optima-KV project combines, or aggregates, the biogas created from the anaerobic digestion of swine waste from five (5) adjacently located farms housing approximately 60,000 finishing pigs. The Optima-KV project includes the construction of an in-ground anaerobic digester at each farm. The resulting biogas is captured from each farm, and routed to an adjacent, centralized biogas upgrading facility, or refinery, where the biogas undergoes purification and cleaning to pipeline quality specifications. The renewable natural gas produced from this system will be sold to an electric utility subject to the requirements of the North Carolina Renewable Energy Portfolio Standards, and will result in reduced emissions from both the receiving electricity generating unit and the farms, reduced emissions of odors from the farms, and reduced fossil fuel consumption for the production of electricity. The upgraded biogas (RNG) will be transmitted to the electricity generating unit through existing natural gas pipeline infrastructure.

What have we learned?

The innovative design, permitting, and financing for the project is very different than a conventional feedstock aggregation approach, and thus much has been learned. To deliver the RNG to the end user, in this case, multiple contracts with multiple utilities were Graphic showing how it works required, which presented challenges of negotiating multiple utility connections and agreements. This learning curve was steepened as, at the time of the inception of Optima KV, the state of North Carolina lacked formal pipeline injection standards, so the final required quality and manner of gas upgrading was established through the development of the project.

The project is currently in the beginning stages of construction, and completion is expected by the end of 2017. Given this schedule, the Optima KV project will provide the first pipeline injection of gas – from any source – in the state of North Carolina (all natural gas presently consumed in the state is sourced from out of state).

Future Plans

North Carolina’s potential for agricultural waste-to-energy projects is enormous, given its vast agricultural resources. Combining the potential from agriculture with the bioenergy potential from wastewater treatment plants and landfills, it is estimated to be third in capacity behind only California and Texas. The unique approach to aggregation of value streams from multiple sources, as exhibited by this project, will open the doors for similar aggregation strategies, including the anaerobic digestion of mixed feedstocks such as food waste, poultry and swine waste, animal mortality, fats, oils and grease and energy crops.

Corresponding author, title, and affiliation

Gus Simmons, P.E., Director of Bioenergy, Cavanaugh & Associates, P.A.

Corresponding author email

gus.simmons@cavanaughsolutions.com

Additional information

http://www.cavanaughsolutions.com/bioenergy/

1-877-557-8923

gus.simmons@cavanaughsolutions.com

https://www.biocycle.net/2016/11/10/anaerobic-digest-67/

March 5, 2019March 6, 2019

Microarthropods as Bioindicators of Soil Health Following Land Application of Swine Slurry

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*Purpose

As producers of livestock and agricultural crops continue to focus significant efforts on improving the environmental, economic, and social sustainability of their systems, increasing the utilization of livestock manure in cropping systems to offset inorganic fertilizer use benefits both sectors of agriculture. However, promoting manure based purely upon nutrient availability may not be sufficient to encourage use of organic versus inorganic fertilizer. The value of livestock manure could increase significantly with evidence of improved soil fertility and quality following manure application. Therefore, understanding the impact of manure addition and application method on both soil quality and biological health is an important step towards improving the value and desirability of manure for agricultural cropping systems.

For edaphic ecosystems, collection, analysis, and categorization of soil microarthropods has proven to be an inexpensive and easily quantified method of gathering information about the biological response to anthropogenic changes to the environment (Pankhurst et al., 1995; Parisi et al., 2005). Arthropods include insects, crustaceans, arachnids, and myriapods; nearly all soils are inhabited by a vast number of arthropod species. Agricultural soils may contain between 1,000 and 100,000 arthropods per square meter (Wallwork, 1976; Crossley et al., 1992; Ingham, 1999). Soil microarthropods show a strong degree of sensitivity to land management practices (Sapkota et al., 2012) and specific taxa are positively correlated with soil health (Parisi et al., 2005). These characteristics make soil microarthropods exceptional biological indicators of soil health.

This study focused on assessing the chemical and biological components of soil health, described in terms of soil arthropod population abundance and diversity, as impacted by swine slurry application method and time following slurry application.

What did we do?

A field study was conducted near Lincoln, Nebraska from June 2014 through June 2015 on a site that has been operated under a no-till management system with no manure application since 1966. Experimental treatments included two manure application methods (broadcast and injected) and a control (no manure applied).

Soil samples were collected twelve days prior to treatment applications, one and three weeks post-application of manure, and every four weeks, thereafter, throughout the study period. Samples were not collected during winter months when soil was frozen.

Two types of soil samples were collected. Samples obtained with a 3.8-cm diameter soil probe were divided into 0-10 and 10-20 cm sections for each of the plots for nutrient analysis at a commercial laboratory. Samples measuring 20 cm in diameter and 20 cm in depth, yielding a soil volume of 6,280 cm3, were stored in plastic buckets with air holes in the lids, placed in coolers with ice packs, and transported to the University of Nebraska-Lincoln West Central Research & Extension Center in North Platte, Nebraska within 12 h of collection. These samples were then transferred to Berlese-Tullgren funnels for extraction of arthropods, a commonly used technique to assess microarthropods in the soil (Ducarme et al., 2002). A 70% ethanol solution was used to preserve the organisms for later analysis.

The QBS method of classification was employed to assign an eco-morphological index (EMI) score on the basis of soil adaptability level of each arthropod order or family (Parisi et al., 2005). Preserved arthropods from each soil sample were identified and quantified using a Leica EZ4 stereo microscope (Leica Biosystems, Inc., Buffalo Grove, IL) and a dichotomous key (Triplehorn and Johnson, 2004). Arthropods were classified to order or family based on the level of taxonomic resolution necessary to assign an EMI value as described by Parisi et al. (2005). For some groups, such as Coleoptera, characteristics of edaphic adaptation were used to assign individual EMI scores.

The impacts of swine slurry application method and time following manure application on soil arthropod populations and soil chemical characteristics was determined by performing tests of hypotheses for mixed model analysis of variance using the general linear model (GLM) procedure (SAS, 2015). The samples were tested for significant differences resulting from time and treatment, as well as for variations within the treatment samples. Following identification of any significant differences, the least significant differences (LSD) test was employed to identify specific differences among treatments. P <0.05 was considered statistically significant.

What have we learned?

A total of 13,311 arthropods representing 19 orders were identified, with Acari (38.7% of total arthropods), Collembola: Isotomidae (26.8%), Collembola: Hypogastruridae (10.4%), Coleoptera larvae (1.6%), Diplura (1.2%), Diptera larvae (0.9%), and Pseudoscorpiones (0.6%) being the most abundant soil-dwelling taxa. These taxa had the greatest relative abundance in samples throughout the study and were, therefore, chosen for statistical analysis of their response to manure application method and time since application.

The most significant responses to application method were found for collembolan populations, specifically for Hypogastruridae and Isotomidae. However, Pseudoscorpiones were also significantly affected by application method. Time following slurry application had a significant impact on most of the analyzed populations including Hypogastruridae, Isotomidae, mites, coleopteran larvae, diplurans, and dipteran larvae. The positive response of Hypogastruridae and Isotomidae collembolans to broadcast swine slurry application was likely due to the addition of nutrients (in the form of OM and nitrates) to the soil provided by this form of agricultural fertilizer.

Future Plans

Research focused on the role of livestock manure in cropping systems for improved soil quality and fertility is underway with additional soil characteristics being monitored under multiple land treatment practices with and without manure.

Corresponding author, title, and affiliation

Dr. Amy Millmier Schmidt, Assistant Professor, University of Nebraska – Lincoln

Corresponding author email

aschmidt@unl.edu

Other authors

Nicole R. Schuster, Julie A. Peterson, John E. Gilley and Linda R. Schott

Additional information

Dr. Amy Millmier Schmidt can also be reached at (402) 472-0877.

Dr. Julie Peterson, Assistant Professor of Entomology, University of Nebraska – Lincoln can be reached at (308) 696-6704 or Julie.Peterson@unl.edu.

Acknowledgements

Eric Davis, Ethan Doyle, Mitchell Goedeken, Stuart Hoff, Kevan Reardon, and Lucas Snethen are gratefully acknowledged for their assistance with field data collection. Kayla Mollet, Ethan Doyle, and Ashley Schmit are acknowledged for their assistance with data processing. This research was funded, in part, by faculty research funds provided by the Agricultural Research Division within the University of Nebraska-Lincoln Institute of Agriculture and Natural Resources.

March 5, 2019March 6, 2019

Livestock Methane Emissions Estimated and Mapped at a County-level Scale for the Contiguous United States

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Purpose

This analysis of methane emissions used a “bottom-up” approach based on animal inventories, feed dry matter intake, and emission factors to estimate county-level enteric (cattle) and manure (cattle, swine, and poultry) methane emissions for the contiguous United States.

What did we do?

Methane emissions from enteric and manure sources were estimated on a county-level and placed on a map for the lower 48 states of the US. Enteric emissions were estimated as the product of animal population, feed dry matter intake (DMI), and emissions per unit of DMI. Manure emission estimates were calculated using published US EPA protocols and factors. National Agricultural Statistic Services (NASS) data was utilized to provide animal populations. Cattle values were estimated for every county in the 48 contiguous states of the United States. Swine and poultry estimates were conducted on a county basis for states with the highest populations of each species and on a state-level for less populated states. Estimates were placed on county-level maps to help visual identification of methane emission ‘hot spots’. Estimates from this project were compared with those published by the EPA, and to the European Environmental Agency’s Emission Database for Global Atmospheric Research (EDGAR).

What have we learned?

Overall, the bottom-up approach used in this analysis yielded total livestock methane emissions (8,888 Gg/yr) that are comparable to current USEPA estimates (9,117 Gg/yr) and to estimates from the global gridded EDGAR inventory (8,657 Gg/yr), used previously in a number of top-down studies. However, the spatial distribution of emissions developed in this analysis differed significantly from that of EDGAR.

Methane emissions from manure sources vary widely and research on this subject is needed. US EPA maximum methane generation potential estimation values are based on research published from 1976 to 1984, and may not accurately reflect modern rations and management standards. While some current research provides methane emission data, a literature review was unable to provide emission generation estimators that could replace EPA values across species, animal categories within species, and variations in manure handling practices.

Future Plans

This work provides tabular data as well as a visual distribution map of methane emission estimates from enteric (cattle) and manure (cattle, swine, poultry) sources. Future improvement of products from this project is possible with improved manure methane emission data and refinements of factors used within the calculations of the project.

Corresponding author, title, and affiliation

Robert Meinen, Senior Extension Associate, Penn State University Department of Animal Science

Corresponding author email

rjm134@psu.edu

Other authors

Alexander Hristov (Principal Investigator), Professor of Dairy Nutrition, Penn State University Department of Animal Science Michael Harper, Graduate Assistant, Penn State University Department of Animal Science Richard Day, Associate Professor of Soil

Additional information

None.

Acknowledgements

Funding for this project was provided by ExxonMobil Research and Engineering.

March 5, 2019March 20, 2019

Biofuels and Bioproducts from Wet and Gaseous Waste Streams: Challenges and Opportunities

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Purpose

To provide an initial characterization of the wet and gaseous organic feedstocks available in the continental U.S., and to explore technological possibilities for converting these streams into biofuels and bioproducts.

What did we do?

The Bioenergy Technologies Office (BETO) of the U.S. Department of Energy commissioned an in depth resource assessment by teams at the the National Renewable Energy Lab (NREL) and the Pacific Northwest National Lab (PNNL). Concurrently, BETO conducted a series of workshops, informed by an extended literature review and several rounds of peer review to ascertain the states of technologies for making biofuels and bioproducts from these resources. These efforts resulted in a January 2017 report that is available here:

https://energy.gov/eere/bioenergy/articles/beto-publishes-analysis-biofu…

What have we learned?

Terrestrial feedstocks are currently the largest resource generated for the bioeconomy, estimated at 572 million dry tons for 2017 (Billion Ton 2016), and have traditionally constituted the primary focus of the Bioenergy Technologies Office (BETO). However, the resource assessment conducted by the National Renewable Energy Lab and Pacific Northwest National Lab indicates that wet waste feedstocks (Summarized in Table ES-1) could also make significant contributions to the bioeconomy and domestic energy security goals.

Summary of Annual Wet and Gaseous Feedstock Availability

Table 1. Annual Resource Generation

1 116,090 Btu/gal. This does not account for conversion efficiency.

2 The moisture content of food waste varies seasonally, ranging from 76% in the summer to 72% in the winter.

3 Methane potential. This does not include currently operational landfill digesters (>1,000 billion cubic feet [Bcf] annually) and may double count potential from wastewater residuals, food waste, and animal waste.

4 DDGS = Dried Distillers Grains with Solubles

BCF- Billion cubic feet

When combining the primary waste streams of interest: sludge/biosolids, animal manure, food waste, and fats, oils, and greases, a supplemental 77 million dry tons per year are generated. Of this total, 27 million dry tons is currently being beneficially used (e.g. fertilizer, biodiesel, compost), leaving 50 million dry tons available for conversion to biofuels, bioproducts or biopower. Gaseous waste streams (biogas and associated natural gas) contribute an additional 734 trillion Btu (TBtu), bringing the total energy potential of these feedstocks to over 2.3 quadrillion Btu. Additionally, these streams contain methane, the second most prevalent greenhouse gas, which constituted 12% of net U.S. emissions in 2014 according to the U.S. Environmental Protection Agency’s (EPA) greenhouse gas inventory. Thus, there is significant potential to valorize these energy dense streams while simultaneously reducing harmful emissions.

As illustrated by example in Figure ES-1, wet and gaseous waste streams are widely geographically distributed, frequently in areas of high population density, affording them unique current and emerging market opportunities. The size of publicly owned treatment works, landfills, rendering operations, and grease collectors overlay with the largest population centers nationwide. Therefore, when compared to terrestrial feedstocks, these waste streams are largely aggregated and any derivative biofuels, bioproducts, or biopower are close to end markets.

Figure ES-1. Spatial distribution and influent range of 14,581 US EPA 2012 Clean Water Needs Survey (CWNS) catalogued treatment plants

At the same time, however, this close proximity to populations markets often correlates with more stringent regulatory landscapes for disposal. Therefore, the value proposition presented by these waste streams commonly includes avoiding disposal costs as opposed to an independent biorefinery that requires stand-alone profitability. Aided by these and related factors, public and private entities are actively exploring and deploying novel solutions for waste stream valorization. Potential competition between biofuels, bioproducts, and other beneficial uses will likely be a key element of future markets, and clearly merits further analytical and modeling investigation.

Future Plans

This report concludes that wet and gaseous organic waste streams represent a significant and underutilized set of feedstocks for biofuels and bioproducts. They are available now, in many cases represent a disposal problem that constitutes an avoided cost opportunity, and are unlikely to diminish in volume in the near future. As a result, at least in the short and medium term, they may represent a low-cost set of feedstocks that could help jump start the Bioeconomy of the Future via niche markets. While much modeling, analysis, and technological de-risking remains to be done in order to bring these feedstocks to market at significant scales, the possible contributions to the overall mission of the Bioenergy Technologies Office merit further attention.

Corresponding author, title, and affiliation

Mark Philbrick, Waste-to-Energy Coordinator, Bioenergy Technologies Office, U.S. Department of Energy

Corresponding author email

mark.philbrick@hq.doe.gov

Other authors

see report

Additional information

Future activities are contingent upon Congressional appropriations.

Acknowledgements

see report

March 5, 2019March 20, 2019

Manure Management Technology Selection Guidance

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Purpose

Manure is an inevitable by-product of livestock production. Traditionally, manure has been land applied for the nutrient value in crop production and improved soil quality.With livestock operations getting larger and, in many cases, concentrating in certain areas of the country, it is becoming more difficult to balance manure applications to plant uptake needs. In many places, this imbalance has led to over-application of nutrients with increased potential for surface water, ground water and air quality impairments. No two livestock operations are identical and manure management technologies are generally quite expensive, so it is important to choose the right technology for a specific livestock operation. Information is provided to assist planners and landowners in selecting the right technology to appropriately address the associated manure management concerns.

What did we do?

As with developing a good conservation plan, knowledge of manure management technologies can help landowners and operators best address resource concerns related to animal manure management. There are so many things to consider when looking at selecting various manure treatment technologies to make sure that it will function properly within an operation. From a technology standpoint, users must understand the different applications related to physical, chemical, and biological unit processes which can greatly assist an operator in choosing the most appropriate technology. By having a good understanding of the advantages and disadvantages of these technologies, better decisions can be made to address the manure-related resource concerns and help landowners:

• Install conservation practices to address and avoid soil erosion, water and air quality issues.

• In the use of innovative technologies that will reduce excess manure volume and nutrients and provide value-added products.

• In the use of cover crops and rotational cropping systems to uptake nutrients at a rate more closely related to those from applied animal manures.

• In the use of local manure to provide nutrients for locally grown crops and, when possible, discourage the importation of externally produced feed products.

• When excess manure can no longer be applied to local land, to select options that make feasible the transport of manure nutrients to regions where nutrients are needed.

• Better understand the benefits and limitations of the various manure management technologies.

Picture of holding tank

Complete-Mix Anaerobic Digester – option to reduce odors and pathogens; potential energy production

Picture of mechanical equipment

Gasification (pyrolysis) system – for reduced odors; pathogen destruction; volume reduction; potential energy production.

Picture of field

Windrow composting – reduce pathogens; volume reduction

Picture of Flottweg separation technology

Centrifuge separation system – multiple material streams; potential nutrient
partitioning.

What have we learned?

• There are several options for addressing manure distribution and application management issues. There is no silver bullet.

• Each livestock operation will need to be evaluated separately, because there is no single alternative which will address all manure management issues and concerns.

• Option selections are dependent on a number of factors such as: landowner objectives, manure consistency, land availability, nutrient loads, and available markets.

• Several alternatives may need to be combined to meet the desired outcome.

• Soil erosion, water and air quality concerns also need to be addressed when dealing with manure management issues.

• Most options require significant financial investment.

Future Plans

Work with technology providers and others to further evaluate technologies and update information as necessary. Incorporate findings into NRCS handbooks and fact sheets for use by staff and landowners in selecting the best technology for particular livestock operations.

Corresponding author, title, and affiliation

Jeffrey P. Porter, P.E.; National Animal Manure and Nutrient Management Team Leader USDA-Natural Resources Conservation Service

Corresponding author email

jeffrey.porter@gnb.usda.gov

Other authors

Darren Hickman, P.E., National Geospatial Center of Excellence Director USDA-Natural Resources Conservation Service; John Davis, National Nutrient Management Specialist USDA-Natural Resources Conservation Service, retired

Additional information

References

USDA-NRCS Handbooks – Title 210, Part 651 – Agricultural Waste Management Field Handbook

USDA-NRCS Handbooks – Title 210, Part 637 – Environmental Engineering, Chapter 4 – Solid-liquid Separation Alternatives for Manure Handling and Treatment (soon to be published)

Webinars

Evaluation of Manure Management Systems – http://www.conservationwebinars.net/webinars/evaluation-of-manure-management-systems/?searchterm=animal waste

Use of Solid-Liquid Separation Alternatives for Manure Handling and Treatment – http://www.conservationwebinars.net/webinars/use-of-solid-liquid-separation-alternatives-for-manure-handling-and-treatment/?searchterm=animal waste

March 5, 2019March 20, 2019

Nutrient Recovery Membrane Technology: Best Applications and Role in Conservation

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Purpose

Animal manure contains nutrients and organic matter that is valuable to crop producers if it can be efficiently applied to nearby fields, however this can be a significant source of environmental contamination if managed incorrectly. In most cases, concentrated animal production facilities are rarely close to sufficient cropland to fully utilize these resources and management becomes a disposal issue rather than a utilization opportunity. The goal of this work is to design and test a pilot-scale system to implement a hydrophobic, gas permeable, expanded polytetraflouroethylene (ePTFE) membrane (U.S. patent held by USDA) to recover ammonia from swine wastewater in a solution of sulfuric acid. The pilot-scale system results are described elsewhere; the purpose of this presentation is to explore the best applications for this and other recovery technologies in animal feeding operations.

What did we do?

The reactor test (figure 1) system consisted of 19 membrane tubes (ID of 0.16 in, wall thickness of 0.023 in) within a 2.01 in diameter, 24.7 in long reactor giving a membrane density of 3.83 in2 in-3 of reactor. Wastewater first passed through a CO2 stripping column (4.016 in diameter, 55 in length) where a small air stream (0.0614 ft 3 min-1) stripped CO2 from the wastewater and raised the pH one full unit, shifting the equilibrium to NH3 and enhancing transport across the membrane. Batch tests (0.706 ft3) were run for 9-12 days with wastewater recirculating at a rate of 0.16 gal min-1. The recovery fluid inside the tubular membranes was a 0.01 N sulfuric acid solution with the pH automatically maintained below 4.0 standard units and recirculating at a rate of 1/100th the wastewater flowrate. Freshly collected settled wastewater and anaerobic digester effluent were tested to determine the mass of ammonia collected, the acid required to main! tain the low pH of the recovery solution and potential ammonia losses to the atmosphere.

Figure 1. Schematic of membrane system

What have we learned?

The batch volumes of the two sources contained about the same mass of nitrogen (35.6 g in freshly collected settled wastewater and 33.2 g in digester effluent) but the higher fraction of ammonia in digester effluent resulted in greater recovery (77% vs. 33%).

Future Plans

The best use of this and other recovery technologies cannot be determined by simply comparing the cost of installation and operation with the price of the recovered product. The question of where and how to implement such recovery technologies requires knowledge of the value added by each process and further needs an understanding of how various practices interact and contribute to a sustainable system. Process interactions will suggest one step come before another because of the characteristics produced by one and needed by the other. Anaerobic digestion effluent has different characteristics than the output of a hydrothermal process. As seen in the membrane results, freshly collected liquid waste has a different ammonia : organic nitrogen ratio than digester effluent. Source separated manure solids have high levels of organic phosphorus but digester effluent has high concentrations of dissolved phosphate.

Product recovery is only the beginning of the valuation process; as an industry and as a society, we value conservation for other reasons. We do not yet have a well-accepted way to quantify that value. The avoided cost of nitrogen removal from surface waters is a good start to estimate the value of keeping nitrogen out of drainage and runoff but what is the quantified value of preserving the ecosystem services that excess nitrogen disrupts? The cost of recovered phosphorus may be high relative the current price of virgin phosphate from ore but the value of that recovery process includes the avoided problems in rivers, lakes, and estuaries caused by excess nutrients. The fertilizer value of recovered ammonia that was prevented from escaping to the atmosphere may be small compared to the avoided cost of particulate pollution and the associated health problems.

In addition to improved operation of the membrane reactor system, at least three things are needed to fully realize the value of resource recovery:

1. Cost-effective dewater processes. Rejecting inert water can reduce the capital and/or operating cost of almost all waste management processes;

2. Process to quantify the value of ecosystem services and avoided costs of recovery;

3. Cooperation of and investment from major stakeholders in the form of research funding as well as collaboration regarding processes and feed stocks for fertilizer and feed formulations. Animal production companies have historically been involved but fertilizer companies, feed mill operators, animal nutritionists and others must also be involved.

Corresponding author, title, and affiliation

John J. Classen, Associate professor, Biological and Agricultural Engineering, NC State University

Corresponding author email

john_classen@ncsu.edu

Other authors

J. Mark Rice, Extension Specialist, Biological and Agricultural Engineering, NC State University, Kelly Zering, Professor and Extension Specialist, Agricultural and Resource Economics, NC State University

Additional information

John J. Classen

Biological and Agricultural Engineering

Campus Box 7625

North Carolina State University

919-515-6755

Acknowledgements

This project was supported by NRCS CIG Award 69-3A75-12-183. The authors are grateful for the analytical work of the BAE Environmental Analysis Laboratory, Dr. Cong Tu, manager.