With depressed electrical prices for produced biogas, many projects are now moving towards business models predicated on production of renewable natural gas (RNG). In order to produce RNG, projects must first clean and upgrade raw biogas to pipeline and/or transportation fuel quality through the use of various engineering approaches. In this presentation, an overview of available and emerging biogas cleaning and upgrading technologies are discussed, highlighting positives, negatives and costs.
Who Should Consider Biogas Cleaning?
The aim of this fact sheet is to provide farmers, third party project developers, regulatory agencies, and other stakeholders with a basic understanding of the chemical composition of renewable natural gas, the most appropriate end use options for dairy digesters, and some of the more common techniques used to clean biogas to RNG quality at dairy digesters.
What did we do?
The authors utilized years of research and industry expertise as well as thorough literature search describe the concept of renewable natural gas and the technologies to clean the biogas. The authors aimed to provide information based on the current literature, but not to favor one technology over another.
What have we learned?
When CHP is the end-use of biogas, the most common biogas purification approach for dairy digesters in the US is to remove water vapor and hydrogen sulfide. Existing projects use a variety of approaches, ranging from biological processes (both post digestion and via oxygen injection into the digester) to physical-chemical absorption processes such as iron type-sponge or activated carbon.
However, if RNG is the end-use a higher degree of purity is required. Often times a dedicated water vapor removal unit and hydrogen sulfide scrubbing unit is still required for removal of the bulk of the hydrogen sulfide mass. Thereafter, water scrubbing or PSA are often used to remove carbon dioxide from biogas, producing an RNG fuel that can be utilized in a variety of different ways. Other technologies exist, however their application on dairy digesters has been rather limited due to concerns related to maturity, cost, and complexity. The best technique is also situation-specific, and therefore, it is critical to understand the mechanics of each purification process, its limitations, and its economics before making a decision.
As electrical rates continue to drop throughout the PNW and US, current and new AD project developers are strongly considering a shift from CHP towards higher value end-uses for biogas, particularly RNG. Interest is increasing due to a growing CNG industry in the US, the decoupling of CNG and diesel prices, and the potential for competitive pricing and high revenues in comparison to fossil-CNG, given existing government incentives. Projects are presently limited and business models must still be proven before wide-scale adoption of biogas upgrading technologies within a dairy digester platform. In addition, concerns historically plaguing CHP projects, related to power purchase agreement pricing, interconnection fees, and scaling are still potentially present within a pipeline fuel model. Nonetheless, the potential exists for a new business model approach to AD projects on US farms.
Future Plans
No future plans.
Authors
Craig Frear, Assistant Professor, Washington State University cfrear@wsu.edu
Nick Kennedy, Associate in Research WSU; Georgine Yorgey, Associate in Research WSU; Dan Evans, President Promus Energy; Jim Jensen, Associate in Research, WSU Energy; Chad Kruger, DIrector WSU CSANR
Additional information
For those seeking additional detail, or information about other technologies, more comprehensive reports and reviews are available (Jensen, 2011; Krich et al., 2005; Ryckebosch et al., 2011). This publication is part of the Anaerobic Digestion Systems Series, which aims to provide information that improves decision-making for anaerobic digestion systems.
Acknowledgements
This research was supported by funding from USDA National Institute of Food and Agriculture, Contract #2012-6800219814; National Resources Conservation Service, Conservation Innovation Grants #69-3A75-10-152; Biomass Research Funds from the WSU Agricultural Research Center; and the Washington State Department of Ecology, Waste 2 Resources Program.
The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2015. Title of presentation. Waste to Worth: Spreading Science and Solutions. Seattle, WA. March 31-April 3, 2015. URL of this page. Accessed on: today’s date.


We teamed up with a grape and a dairy producer and we built a series of windrows to showcase the three different composting techniques and to research the effects of mixing both waste streams. Grape vine prunings were grounded and mixed with open lot dairy manure. Carbon content of the mix was adjusted to meet organic production standards since the vineyard hosting the project was certified organic. Since the carbon to nitrogen ratio (C:N) of the grounded grape vine prunings was on the low side (80:1), horse stable sawdust and straw from the local county fairgrounds were also used to help increase the C:N. Three replications of each system (MT, PA, and FA) were built with the enhanced carbon mix. A third set of three replications with dairy manure as received (some straw but no added carbon) were built using the mechanically turned system (MTMA) to serve as a control and comparison for that system. In addition to collecting data to evaluate th e effects of the added carbon, the project included two field days where all the systems, how to construct them, and their advantages and challenges were showcased.
The initial feedstock mix C:N was significantly higher in the carbon enhanced windrows as expected, but the final C:N ratio of the compost was not significantly different among most systems and between the enhanced mix and the just manure mix (Figure 1). The C:N reduction between the initial mix and the final compost was significant in all systems of the carbon enhanced windrows, but not significant in the just manure mix (MTMA).
As expected, the initial mix total nitrogen (TN) was significantly lower in the carbon (C) enhanced windrows compared to the just manure windrows (Figure 2). TN in the finished compost had no significant difference among all the systems. The difference between the initial mix and final compost TN wasn’t significant among C enhanced windrows, but highly significant in net values (10.08 Lb/T of N on dry weight basis; p<0.0001) on the just manure windrows. This difference in TN, coupled with the no significant difference in C:N, suggests the loss of nitrogen as ammonia during the composting process in the windrows made of just manure. Net nitrogen loss was significantly lower in the C enhanced windrows (1.45 Lb/Ton).
Salts concentrations (mmhos) difference between initial mixes and final compost was significant in all windrows, with higher values in the final compost as expected due to the concentration effect that composting volume reduction has (Figure 3). Salt concentrations in the just manure windrows were significantly higher compared to the carbon enhanced mix. There is a dilution effect when carbon is added in the initial mix (lower manure mass per initial mix unit). Similar dilution trends were observed for phosphorous (P), potassium (K), and micronutrients. Carrying this dilution effect in the final compost can be beneficial when land applying compost since application rates can be increased, increasing the nitrogen and carbon content of the application (desirable conditions) by the time the limiting components in our soils (usually P, K, or salts) are reached.









Feed ingredients with highest costs are additives (e.g. paylean) and amino acids. Milk by-products have the largest climate change impact, water and land use.