Tag: volatile organic compounds

Posted on

Production of Greenhouse Gases, Ammonia, Hydrogen Sulfide, and Odorous Volatile Organic Compounds from Manure of Beef Feedlot Cattle Implanted with Anabolic Steroids

Animal production is part of a larger agricultural nutrient recycling system that includes soil, water, plants, animals and livestock excreta. When inefficient storage or utilization of nutrients occurs, parts of this cycle become overloaded. The U.S. Beef industry has made great strides in improving production efficiency with a significant emphasis on improving feed efficiency. Improved feed efficiency results in fewer excreted nutrients and volatile organic compounds (VOC) that impair environmental quality. Anabolic steroids are used to improve nutrient feed efficiency which increases nitrogen retention and reduces nitrogen excretion. This study was conducted to determine the methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O), odorous VOCs, ammonia (NH3), and hydrogen sulfide (H2S) production from beef cattle manure and urine when aggressive steroid implants strategies were used instead of moderate implant strategies.

What Did We Do?

Two groups of beef steers (60 animals per group) were implanted using two levels of implants (moderate or aggressive). This was replicated three times, twice with spring-born calves and once with fall-born calves, for a total of 360 animals used during the study. Both moderate and aggressive treatment groups received the same initial implant that contain 80 mg trenbolone acetate and 16 mg estradiol. At second implant, steers in the moderate group received an implant that contained 120 mg trenbolone acetate and 24 mg estradiol, while those in the aggressive group received an implant that contained 200 mg trenbolone acetate and 20 mg estradiol. Urine and feces samples were collected individually from 60 animals that received a moderate implant and 60 animals that received an aggressive implant at each of three sampling dates (Spring and Fall 2017 and Spring 2018). Within each treatment, fresh urine and feces from five animals were mixed together to make a composite sample slurry (2:1 ratio of manure:urine) and placed in a petri dish. There were seven composite mixtures for each treatment at each sampling date. Wind tunnels were used to pull air over the petri dishes. Ammonia, carbon dioxide, and nitrous oxide concentrations were measured using an Innova 1412 Photoacoustic Gas Analyzer. Hydrogen sulfide and methane were measured using a Thermo Fisher Scientific 450i and 55i, respectively. Gas measurements were taken a minimum of six times over 24- to 27-day sampling periods.

What Have We Learned?

Flux of ammonia, hydrogen sulfide, methane, nitrous oxide, and total aromatic volatile organic compounds were significantly lower when an aggressive implant strategy was used compared to a moderate implant strategy. However, the flux of total branched-chained volatile organic compounds from the manure increased when aggressive implants were used compared to moderate implants. Overall, this study suggests that air quality may be improved when an aggressive implant is used in beef feedlot animals.

Table 1. Overall average flux of compounds from manure (urine + feces) from beef feedlot cattle implanted with a moderatea or aggressiveb anabolic steroid.
Hydrogen Sulfide Ammonia Methane Carbon Dioxide Nitrous  Oxide Total Sulfidesc Total SCFAd Total BCFAe Total Aromaticsf
µg m-2 min-1 ——–mg m-2 min-1——–
Moderate 4.0±0.1 2489.7±53.0 117.9±4.0 8795±138 8.6±0.1 0.7±0.1 65.2±6.6 5.9±0.5 2.9±0.3
Aggressive 2.7±0.2 2186.4±46.2 104.0±3.8 8055±101 7.4±0.1 0.8±0.1 63.4±5.7 7.6±0.8 2.1±0.2
P-value 0.01 0.04 0.01 0.01 0.01 0.47 0.83 0.05 0.04
aModerate treatment =  120 mg trenbolone acetate and 24 mg estradiol at second implant; bAggressive treatment = 200 mg trenbolone acetate and 20 mg estradiol at second implant; cTotal sulfides = dimethyldisulfide and dimethyltrisulfide; dTotal straight-chained fatty acids (SCFA) = acetic acid, propionic acid, butyric acid, valeric acid, hexanoic acid, and heptanoic acid;  eTotal branch-chained fatty acids (BCFA) = isobutyric acid and isovaleric acid; fTotal aromatics = phenol, 4-methylphenol, 4-ethylphenol, indole, and skatole

Future Plans
Urine and fecal samples are being evaluated to determine the concentration of steroid residues in the livestock waste and the nutrient content (nitrogen, phosphorus, potassium and sulfur) of the urine and feces.

Authors

mindy.spiehs@ars.usda.gov Mindy J. Spiehs, Research Animal Scientist, USDA ARS Meat Animal Research Center, Clay Center, NE

Bryan L. Woodbury, Agricultural Engineer, USDA ARS Meat Animal Research Center, Clay Center, NE

Kristin E. Hales, Research Animal Scientist, USDA ARS Meat Animal Research Center, Clay Center, NE

Additional Information

Will be included in Proceedings of the 2019 Annual International Meeting of the American Society of Agricultural and Biological Engineers.

USDA is an equal opportunity provider and employer. 

Acknowledgements

The authors wish to thank Alan Kruger, Todd Boman, Bobbi Stromer, Brooke Compton, John Holman, Troy Gramke and the USMARC Cattle Operations Crew for assistance with data collection.

The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2019. Title of presentation. Waste to Worth. Minneapolis, MN. April 22-26, 2019. URL of this page. Accessed on: today’s date.

Posted on

Production of Greenhouse Gases and Odorous Compounds from Manure of Beef Feedlot Cattle Fed Diets With and Without Ionophores

Ionophores are a type of antibiotics that are used in cattle production to shift ruminal fermentation patterns. They do not kill bacteria, but inhibit their ability to function and reproduce. In the cattle rumen, acetate, propionate, and butyrate are the primary volatile fatty acids produced. It is more energetically efficient for the rumen bacteria to produce acetate and use methane as a hydrogen sink rather than propionate. Ionophores inhibit archaea forcing bacteria to produce propionate and butyrate as hydrogen sinks rather than working symbiotically with methanogens to produce methane as a hydrogen sink. Numerous research studies have demonstrated performance advantages when ionophores are fed to beef cattle, but few have considered potential environmental benefits of feeding ionophores. This study was conducted to determine if concentrations of greenhouse gases, odorous volatile organic compounds (VOC), ammonia, and hydrogen sulfide from beef cattle manure could be reduced when an ionophore was fed to finishing cattle.

What Did We Do?

Four pens of feedlot cattle were fed an ionophore (monensin) and four pens received no ionophore (n=30 animals/pen). Samples were collected six times over a two-month period. A minimum of 20 fresh fecal pads were collected from each feedlot pen at each collection. Samples were mixed within pen and a sub-sample was placed in a small wind-tunnel. Duplicate samples for each pen were analyzed. Ammonia, carbon dioxide (CO2), and nitrous oxide (N2O) concentrations were measured using an Innova 1412 Photoacoustic Gas Analyzer. Hydrogen sulfide (H2S) and methane (CH4) were measured using a Thermo Fisher Scientific 450i and 55i, respectively.

What Have We Learned?

 

Table 1. Overall average concentration of compounds from feces of beef feedlot cattle fed diets with and without monensin.
Hydrogen Sulfide Ammonia Methane Carbon Dioxide Nitrous  Oxide Total Sulfidesa Total  SCFAb Total BCFAc Total Aromaticsd
µg L-1 —————-mg L-1—————-
No Monensin 87.3±2.2 1.0±0.2 4.3±0.1 562.5±2.2 0.4±0.0 233.4±18.3 421.6±81.9 16.8±3.1 83.7±6.4
Monensin 73.9±1.4 1.1±0.2 3.2±0.2 567.1±2.1 0.5±0.0 145.5±10.9 388.9±32.5 20.3±2.3 86.4±5.6
P-value 0.30 0.40 0.01 0.65 0.21 0.01 0.79 0.48 0.75
aTotal sulfides = dimethyldisulfide and dimethyltrisulfide; bTotal straight-chained fatty acids (SCFA) = acetic acid, propionic acid, butyric acid, valeric acid, hexanoic acid, and heptanoic acid;  cTotal branch-chained fatty acids (BCFA) = isobutyric acid and isovaleric acid; dTotal aromatics = phenol, 4-methylphenol, 4-ethylphenol, indole, and skatole

Total CH4 concentration decreased when monensin was fed. Of the VOCs measured, only total sulfide concentration was lower for the manure from cattle fed monensin compared to those not fed monensin. Ammonia, N2O, CO2, H2S, and all other odorous VOC were similar between the cattle fed monensin and those not fed monensin. The results only account for concentration of gases emitted from the manure and do not take into account any urinary contributions, but indicate little reduction in odors and greenhouse gases when monensin was fed to beef finishing cattle.

Future Plans

A study is planned for April – July 2019 to measure odor and gas emissions from manure (urine and feces mixture) from cattle fed with and without monensin. Measurements will also be collected from the feedlot surface of pens with cattle fed with and without monensin.  

Authors

Mindy J. Spiehs, Research Animal Scientist, USDA ARS Meat Animal Research Center, Clay Center, NE

mindy.spiehs@ars.usda.gov

Bryan L. Woodbury, Agricultural Engineer, USDA ARS Meat Animal Research Center, Clay Center, NE

Kristin E. Hales, Research Animal Scientist, USDA ARS Meat Animal Research Center, Clay Center, NE

Additional Information

Dr. Hales also looked at growth performance and E. coli shedding when ionophores were fed to finishing beef cattle. This work is published in Journal of Animal Science.

Hales, K.E., Wells, J., Berry, E.D., Kalchayanand, N., Bono, J.L., Kim, M.S. 2017. The effects of monensin in diets fed to finishing beef steers and heifers on growth performance and fecal shedding of Escherichia coli O157:H7. Journal of Animal Science. 95(8):3738-3744. https://pubmed.ncbi.nlm.nih.gov/28805884/.

USDA is an equal opportunity provider and employer.

Acknowledgements

The authors wish to thank Alan Kruger, Todd Boman, and the USMARC Cattle Operations Crew for assistance with data collection.

The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2019. Title of presentation. Waste to Worth. Minneapolis, MN. April 22-26, 2019. URL of this page. Accessed on: today’s date.

Posted on

Evaluation of current products for use in deep pit swine manure storage structures for mitigation of odors and reduction of NH3, H2S, and VOC emissions from stored swine manure

The main purpose of this research project is an evaluation of the current products available in the open marketplace for using in deep pit swine manure structure as to their effectiveness in mitigation of odors and reduction of hydrogen sulfide (H2S), ammonia (NH3), 11 odorous volatile organic compounds (VOCs) and greenhouse gas (CO2, methane and nitrous oxide) emissions from stored swine manure. At the end of each trial, hydrogen sulfide and ammonia concentrations are measured during and immediately after the manure agitation process to simulate pump-out conditions. In addition, pit manure additives are tested for their impact on manure properties including solids content and microbial community.

What Did We Do?

Figure 1. Reactor simulates swine manure storage with controlled air flow rates.

We are using 15 reactors simulating swine manure storage (Figure 1) filled with fresh swine manure (outsourced from 3 different farms) to test simultaneously four manure additive products using manufacturer recommended dose for each product. Each product is tested in 3 identical dosages and storage conditions. The testing period starts on Day 0 (application of product following the recommended dosage by manufacturer) with weekly additions of manure from the same type of farm. The headspace ventilation of manure storage is identical and controlled to match pit manure storage conditions. Gas and odor samples from manure headspace are collected weekly. Hydrogen sulfide and ammonia concentrations are measured in real time with portable meters (both are calibrated with high precision standard gases). Headspace samples for greenhouse gases are collected with a syringe and vials, and analyzed with a gas chromatograph calibrated for CO2, methane and nitrous oxide. Volatile organic compounds are collected with solid-phase microextraction probes and analyzed with a gas chromatography-mass spectrometry (Atmospheric Environment 150 (2017) 313-321). Odor samples are collected in 10 L Tedlar bags and analyzed using the olfactometer with triangular forced-choice method (Chemosphere, 221 (2019) 787-783). To agitate the manure for pump-out simulation, top and bottom ‘Manure Sampling Ports’ (Figure 1) are connected to a liquid pump and cycling for 5 min. Manure samples are collected at the start and end of the trial and are analyzed for nitrogen content and bacterial populations.

The effectiveness of the product efficacy to mitigate emissions is estimated by comparing gas and odor emissions from the treated and untreated manure (control). The mixed linear model is used to analyze the data for statistical significance.

What we have learned?

Figure 2. Hydrogen sulfide and ammonia concentration increased greatly during agitation process conducted at the end of trial to simulate manure pump-out conditions and assess the instantaneous release of gases. The shade area is the initial 5 minutes of continuous manure agitation.

U.S. pork industry will have science-based, objectively tested information on odor and gas mitigation products. The industry does not need to waste precious resources on products with unproven or questionable performance record. This work addresses the question of odor emissions holistically by focusing on what changes that are occurring over time in the odor/odorants being emitted and how does the tested additive alter manure properties including the microbial community. Additionally, we tested the hydrogen sulfide and ammonia emissions during the agitation process simulating pump-out conditions. For both gases, the emissions increased significantly as shown in Figure 2. The Midwest is an ideal location for swine production facilities as the large expanse of crop production requires large fertilizer inputs, which allows manure to be valued as a fertilizer and recycled and used to support crop production.

Future Plans

We develop and test sustainable technologies for mitigation of odor and gaseous emissions from livestock operations. This involves lab-, pilot-, and farm-scale testing. We are pursuing advanced oxidation (UV light, ozone, plant-based peroxidase) and biochar-based technologies.

Authors

Baitong Chen, M.S. student, Iowa State University

Jacek A. Koziel*, Prof., Iowa State University (koziel@iastate.edu)

Daniel S. Andersen, Assoc. Prof., Iowa State University

David B. Parker, Ph.D., P.E., USDA-ARS-Bushland

Additional Information

  • Heber et al., Laboratory Testing of Commercial Manure Additives for Swine Odor Control. 2001.
  • Lemay, S., Stinson, R., Chenard, L., and Barber, M. Comparative Effectiveness of Five Manure Pit Additives. Prairie Swine Centre and the University of Saskatchewan.
  • 2017 update – Air Quality Laboratory & Olfactometry Laboratory Equipment – Koziel’s Lab. doi: 10.13140/RG.2.2.29681.99688.
  • Maurer, D., J.A. Koziel. 2019. On-farm pilot-scale testing of black ultraviolet light and photocatalytic coating for mitigation of odor, odorous VOCs, and greenhouse gases. Chemosphere, 221, 778-784; doi: 10.1016/j.chemosphere.2019.01.086.
  • Maurer, D.L, A. Bragdon, B. Short, H.K. Ahn, J.A. Koziel. 2018. Improving environmental odor measurements: comparison of lab-based standard method and portable odour measurement technology. Archives of Environmental Protection, 44(2), 100-107.  doi: 10.24425/119699.
  • Maurer, D., J.A. Koziel, K. Bruning, D.B. Parker. 2017. Farm-scale testing of soybean peroxidase and calcium peroxide for surficial swine manure treatment and mitigation of odorous VOCs, ammonia, hydrogen sulfide emissions. Atmospheric Environment, 166, 467-478. doi: 10.​1016/​j.​atmosenv.​2017.​07.​048.
  • Maurer, D., J.A. Koziel, J.D. Harmon, S.J. Hoff, A.M. Rieck-Hinz, D.S Andersen. 2016. Summary of performance data for technologies to control gaseous, odor, and particulate emissions from livestock operations: Air Management Practices Assessment Tool (AMPAT). Data in Brief, 7, 1413-1429. doi: 10.1016/j.dib.2016.03.070.

Acknowledgments

We are thankful to (1) National Pork Board and Indiana Pork for funding this project (NBP-17-158), (2) cooperating farms for donating swine manure and (3) manufacturers for providing products for testing. We are also thankful to coworkers in Dr. Koziel’s Olfactometry Laboratory and Air Quality Laboratory, especially Dr. Chumki Banik, Hantian Ma, Zhanibek Meiirkhanuly, Lizbeth Plaza-Torres, Jisoo Wi, Myeongseong Lee, Lance Bormann, and Prof. Andrzej Bialowiec.

 

The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2019. Title of presentation. Waste to Worth. Minneapolis, MN. April 22-26, 2019. URL of this page. Accessed on: today’s date.

 

Posted on

Diet, Tillage and Soil Moisture Effects on Odorous Emissions Following Land Application of Beef Manure

 

Figure1.  Gas sampling equipment used during the study.

Waste to Worth: Spreading science and solutions logoWaste to Worth home | More proceedings….

Abstract

Little information is currently available concerning odor emissions following land application of beef cattle manure. This study was conducted to measure the effects of diet, tillage, and time following land application of beef cattle manure on the emission of volatile organic compounds (VOC).

Each of the experimental treatments which included tillage (broadcast or disked) and diet (0, 10, or 30% wet distillers grain (WDGS)) were replicated twice. A 5-m tandem finishing disc was used to incorporate the manure to a depth of approximately 8 cm.  Small plots (0.75 m x 2.0 m) were constructed using 20 cm-wide sheet metal frames. A flux chamber was used to obtain air samples within the small plots at 0, 1, 2, 6, and 23 hours following manure application. The flux of fifteen VOC including fatty acids, aromatic compounds, and sulfur containing compounds were measured. Based on odor threshold, isolavleric acid, butyric acid, and 4-methylphenol provided 28.9%, 18.0%, and 17.7%, respectively, of the total measured odor activity. Heptanic acid, acetic acid, skatole, 4-methyphenol, and phenol each contributed less than 1% of the total odor activity. Dimethy disulfide (DMDS) and dimethyl trisulfide were the only measured constituents that were significantly influenced by diet.

DMDS values were significantly greater for the manure derived from the 30% WDGS diet than the other manure sources. No significant differences in DMDS values were found for manure derived from diets containing 0% and 10% WDGS. Tillage did not significantly affect any of the measured VOC compounds. Each of the VOC was significantly influenced by the length of time that had expired following land application. In general, the smallest VOC measurements were obtained at the 23 hour sampling interval.  Diet, tillage, and time following application should each be considered when estimating VOC emissions following land application of beef cattle manure.

Why Study Factors Affecting Manure Application Odors?

Measure the effects of diet, tillage and soil moisture on odor emissions follow land applied beef manure.

Figure 2.  Relative contribution of odorant to the total odor activity.

What Did We Do?

Twelve plots were established across a hill slope. Treatments were tillage (broadcast or disked) and diet (0%, 10%, or 30% WDGS).  Beef manure was applied at 151 kg N ha-1 yr-1.  Gas samples were collected using small wind tunnels and analyzed using a TD-GC-MS. (Fig. 1).  VOC samples were collected at 0, 1, 2, 6, and 23 hours following manure application.  A single application of water was applied and the gas measurement procedure was repeated. The effects of tillage, diet, test interval, and the sample collection time on VOC measurements were determined using ANOVA (SAS Institute, 2011).

What Have We Learned?

Isovaleric acid, butyric acid, and 4-methylphenol accounted for 28.9%, 18.0%, and 17.7%, respectively of the total odor activity (Fig. 2). Dimethyl disulfide (DMDS) and dimethyl trisulfide (DMTS) emissions were significantly increased by the 30 % WDGS diet. The flux increase for DMDS was over 4 times greater for the 30% WDGS diets. Tillage did not significantly affect any of the measured VOC compounds. The largest propionic, isobutric, butyric, isovaleric, and valeric acid measurements occurred with no-tillage under dry condition (Fig. 3A-E). Generally, measured values for these constituents were significantly greater at the 0, 1, 2, and 6 hour sampling intervals than at the 23 hour interval (Fig. 3A-E). The larger emissions for no-till, dry conditions may be due to the drying effect resulting when the manure was broadcast on the surface.  As the manure begins to dry, the water soluble VOCs are released from solution.  The tilled and wet conditions would reduce its release of VOC due to the increased moisture conditions.

Figure 3. Flux values for propionic, isobutyric, butyric, isovaleric , valeric acid and indole as affected by tillage, soil moisture, and time.

Future Plans

Additional studies are planned to quantify the moisture and temperature effect on odorous emissions.

Authors

Bryan L. Woodbury, Research Agricultural Engineer, USDA-ARS,  bryan.woodbury@ars.usda.gov

John E. Gilley, Research Agricultural Engineer, USDA-ARS;

David B. Parker, Professor and Director, Commercial Core Laboratory, West Texas A&M University;

David B. Marx, Professor Statistics, University of Nebraska-Lincoln;

Roger A. Eigenberg, Research Agricultural Engineer, USDA-ARS

Additional Information

http://www.ars.usda.gov/Main/docs.htm?docid=2538

Acknowledgements

We would like to thank Todd Boman, Sue Wise, Charlie Hinds and Zach Wacker for their invaluable help on making this project a success.

The authors are solely responsible for the content of these proceedings. The technical information does not necessarily reflect the official position of the sponsoring agencies or institutions represented by planning committee members, and inclusion and distribution herein does not constitute an endorsement of views expressed by the same. Printed materials included herein are not refereed publications. Citations should appear as follows. EXAMPLE: Authors. 2013. Title of presentation. Waste to Worth: Spreading Science and Solutions. Denver, CO. April 1-5, 2013. URL of this page. Accessed on: today’s date.

Posted on

Mitigation of Odor and Pathogens from CAFOs with UV/TIO2: Exploring Cost Effectiveness

Reprinted, with permission, from the proceedings of: Mitigating Air Emissions From Animal Feeding Operations Conference.

This Technology is Applicable To:

Species: Swine, Poultry
Use Area: Animal Housing
Technology Category: Air Treatment (UV Photocatalysis)
Air Mitigated Pollutants: Volatile Organic Compounds, Odor, Pathogens

System Summary

Odor and target VOCs responsible for livestock odor are mitigated by UV-185 nm (‘deep’ UV) in presence of TiO2 as a catalyst into less odorous or odorless products such as CO2 and H2O. Percent removals from 80 to 99% were measured in lab-scale experiments involving simulated livestock VOCs/odorants and 1 sec irradiation with a low wattage 5.5 W lamp. Selected VOCs simulating livestock odor included p-cresol, sulfur-containing VOCs, and volatile fatty acids. Treatment cost of $0.25 per pig and continuous operation during growing cycle was estimated when the lab-scale results were extrapolated to typical ventilation rates and electricity cost at a swine finish operation in rural Iowa. The long-term goal is to develop cost-effective technology for the simultaneous treatment of odor and pathogens in livestock housing through logical progression of testing from lab-scale, through pilot-scale and finally at commercial scale. Such treatment would be applicable to both the inflow (for airborne pathogen control) and outflow air (for odor and pathogen control) at typical existing and new mechanically-ventilated barns.

Applicability and Mitigating Mechanism

  • Removal of VOCs and responsible for livestock odor in simulated barn air exhaust with UV light and advanced oxidation.
  • Research continues to move this technology from lab to commercial applications.
  • Potentially applicable to both the inflow (for airborne pathogen control) and outflow air (for odor and pathogen control) at typical existing and new mechanically-ventilated barns
  • On-demand, intermittent operation.

Limitations

  • This technology is still under development
  • Cost estimates are extrapolated from lab-scale experiments
  • Effects of particulate matter on UV treatment needs to be investigated
  • Effectiveness and costs associated long-term full-scale operation are not known at this time.

Cost

Treatment cost of $0.25 per pig and continuous operation during growing cycle was estimated when the lab-scale results were extrapolated to typical ventilation rates and electricity cost at a swine finish operation in rural Iowa. This cost could be further reduced for intermittent, on-demand operation. The capital costs would be mainly cost of ‘on-the-shelf’ deep’ UV lamps (currently at $90 for 10W lamp) and the cost of retrofitting of barn exhaust.

Authors

Jacek A. Koziel1,Xiuyan Yang1, Tim Cutler1, Shicheng Zhang1, Jeffrey Zimmerman1, Steven J. Hoff1, William Jenks1, Hans Van Leeuwen1, Yael Laor2, Uzi Ravid3, Robert Armon31Iowa State University, 2’Ya’ar Research Center, Agricultural Research Organization, Israel, 3Faculty of Civil and Environmental Engineering Technion, Haifa, Israel
Point of Contact:
Jacek Koziel, koziel@iastate.edu

The information provided here was developed for the conference Mitigating Air Emissions From Animal Feeding Operations Conference held in May 2008. To obtain updates, readers are encouraged to contact the author.

Posted on

Biofiltration: Mitigation for Odor and Gas Emissions from Animal Operations

Reprinted, with permission, from the proceedings of: Mitigating Air Emissions From Animal Feeding Operations Conference.

The proceedings, “Mitigating Air Emissions from Animal Feeding Operations”, with expanded versions of these summaries can be purchased through the Midwest Plan Service.

This Technology is Applicable To:

Species: Swine, Dairy
Use Area: Animal Housing
Technology Category: Biofilter
Air Mitigated Pollutants: Hydrogen Sulfide, Ammonia, Methane, Volatile Organic Compounds, Odors

System Summary

A biofilter is simply a porous layer of organic material, typically wood chips or a mixture of compost and wood chips, that supports a population of microbes. Odorous building exhaust air is forced through this material and is converted by the microbes to carbon dioxide and water. The compounds in the air are transferred to a wet biofilm that grows on the filter material where microorganisms breakdown the odorous compounds.

Biofiltration can reduce odor and hydrogen sulfide (H2S) emissions by as much as 95% and ammonia by 65%. The method has been used in industry for many years and was recently adapted for use in livestock and poultry systems. Biofilters work in mechanically ventilated buildings or on the pit fans of naturally ventilated buildings. Biofilters can also treat air vented from covered manure storage.

Two configurations of biofilters are being used to treat exhaust air from swine buildings: a horizontal media bed and a vertical media bed. Horizontal biofilters require more land area but are less expensive than vertical biofilters. Horizontal beds can be shallow (< 0.45 m) or deep (> 0.75 m).

Applicability and Mitigating Mechanism

Key factors influencing biofilter size and performance:

  • time the odorous gases spend in the biofilter
  • volume of air treated
  • moisture content of the filter material
  • sizing the biofilter media volume
  • selecting fans capable to push the air through the biofilter
  • choosing biofilter media

Limitations

  • Biofilters are only effective when there is a captured air stream
  • Media moisture content effects the biofilter performance, i.e. dry media results in poor odor reduction
  • Media porosity is related to the fan’s ability to move air through the biofilter. If media is less than 50% porosity most agriculture ventilation fans will not perform satisfactorily

Cost

Costs to install a biofilter include the cost of the materials—fans, media, ductwork, plenum—and labor. Typically, cost for new horizontal biofilter on mechanically ventilated buildings will be between $150 and $250 per 1,700 m3/hr (1,000 cfm). A vertical biofilter is approximately 1.5 times the cost of a horizontal biofilter. Annual operation/maintenance of the biofilter is estimated to be $5-$10 per 1,700 m3/hr (1,000 cfm). This includes the increase in electrical costs to push the air through the biofilter and the cost of replacing the media after 5 years.

Authors

R.E. Nicolai1, K.J. Janni2, D.R. Schmidt21South Dakota State University, 2University of Minnesota
Point of Contact:
Richard Nicolai, richard.nicolai@sdstate.edu

The information provided here was developed for the conference Mitigating Air Emissions From Animal Feeding Operations Conference held in May 2008. To obtain updates, readers are encouraged to contact the author.

Posted on

Effects of Waste Management Techniques to Reduce Dairy Emissions from Freestall Housing

Reprinted, with permission, from the proceedings of: Mitigating Air Emissions From Animal Feeding Operations Conference.

The proceedings, “Mitigating Air Emissions from Animal Feeding Operations”, with expanded versions of these summaries can be purchased through the Midwest Plan Service.

This Technology is Applicable To:

Species: Dairy
Use Area: Animal Housing
Technology Category: Management
Air Mitigated Pollutants: Volatile Organic Compounds, Ethanol & Methanol

System Summary

Recent dairy emission research has identified alcohols (methanol and ethanol) as the major volatile organic compound (VOC) group originating from fresh waste (Shaw et al., 2007; Sun et al., 2008). Effective control of these alcohols from dairies will help the dairy industry meet regulatory standards, satisfy public concerns, and improve local and regional air quality. Enhancing industry typical freestall waste management practices, which currently are predominant practices like flushing and scraping of fresh waste, may provide a large impact on mitigation of oxygenated VOC emissions in a cost effective manner.

Our research has shown that flushing is more effective than scraping in reducing methanol (MeOH) and ethanol (EtOH) emissions from barns. Flushing three times daily versus scraping three times daily yields an emission reduction efficiency of 50% for both MeOH and EtOH. Furthermore, flushing frequency by itself significantly reduces emissions. A comparison of 3 times versus 6 times flushing daily showed decreased emissions by 79% for MeOH and 63% for EtOH.

Applicability and Mitigating Mechanism

  • Oxygenated VOC (e.g., alcohols MeOH and EtOH) are produced by fermenting microbes present in fresh waste
  • Frequent waste removal effectively mitigates MeOH and EtOH emissions from fresh waste
  • VOC alcohols are water-soluble and become effectively trapped in water when flushed
  • Flushing is more effective than scraping, and increasing flushing frequency further decreases VOC emissions

Limitations

  • Scraping methods leave a thin film of manure on concrete ground that continues to produce emissions

Cost

There is no cost associated with increasing the flushing frequency of a liquid manure handling system. Essentially, flushing frequency is increased, while the amount of water per flushing event is decreased. Since the water used to flush barns is recycled water from the lagoons, there is no cost to re-circulate lagoon water through the barn alleys.

Authors

M. Calvo, K. Stackhouse, Y. Zhao, Y. Pan, Ts Armitage, and F. Mitloehner, University of California, Davis
Point of Contact:
Frank Mitloehner, fmmitloehner@ucdavis.edu

The information provided here was developed for the conference Mitigating Air Emissions From Animal Feeding Operations Conference held in May 2008. To obtain updates, readers are encouraged to contact the author.

Posted on

Use of Sodium Bisulfate to Reduce Ammonia Emissions from Poultry and Livestock Housing

Reprinted, with permission, from the proceedings of: Mitigating Air Emissions From Animal Feeding Operations Conference.

The proceedings, “Mitigating Air Emissions from Animal Feeding Operations”, with expanded versions of these summaries can be purchased through the Midwest Plan Service.

This Technology is Applicable To:

Species: Poultry (Broiler, Layer, and Turkey), Beef, horses
Use Area: Animal Housing
Technology Category: Chemical Amendment
Air Mitigated Pollutants: Ammonia, Volatile Organic Compounds (VOCs)

System Summary

The application of Sodium bisulfate (SBS) has been shown to effectively reduce ammonia emissions from poultry housing, horse stalls, and dairy facilities. In addition, VOC emissions from fresh cattle manure are also greatly reduced (Marsh Johnson, et al. 2006, Ullman, et al., 2004; Blake and Hess, 2001; Sweeney, et al., 1996; Harper, 2002, Sun et al, 2008). Currently, 40-50% of all broilers produced in the United States are raised on SBS treated litter (PLT® litter acidifier, Jones-Hamilton Co., Walbridge, OH) for the purpose of controlling interior ammonia levels below 20 PPM and reducing litter bacterial levels for bird welfare and performance reasons. In addition to reducing ammonia emissions by 60% from fresh dairy manure, ethanol and methanol emissions were also reduced 61% and 58%, respectively (Sun, et al. 2008). Sodium bisulfate is broadcast over the surface of the bedding material and can be applied in the presence of poultry and livestock.

Sodium bisulfate is a dry, granular acid salt. Current application rates are dependent on litter age, animal density, and other factors and range from 0.32-1.95 kg/m2 (50-300 lbs/1000 sqft) of animal housing space. Decreasing interior ammonia concentrations in poultry housing allow for a reduced ventilation rate leading to substantial fuel savings of up to 43% with sodium bisulfate application (Terzich, 1997). In addition, sodium bisulfate usage improves bird performance, reduces pathogens on poultry carcasses, and decreases poultry respiratory lesions and ascites (Pope and Cherry, 2000; Terzich et al, 1998 a & b).

Applicability and Mitigating Mechanism

  • SBS reduces litter and bedding pH reducing ammonia flux
  • SBS reacts with ammonia to form ammonium sulfate preventing release of ammonia as pH increases over time
  • The combination of sodium and hydrogen reduce manure bacterial populations thereby reducing VOC emissions and pathogens
  • SBS can be safely applied in the presence of animals or prior to animal placement

Limitations

  • SBS application rates need to be increased as ammonia demand in the litter increases

Cost

Sodium bisulfate costs $0.50/kg ($0.23/lb) and the use of a commercial applicator is approximately $40-45 per house. SBS is safe enough to be applied by the farmer or poultry grower. No additional house preparation is necessary for application. Fuel savings in the first 2-3 days recoup the cost of SBS and its application. Improvements in feed conversion, weight, livability, and paw quality all provide substantial additional return on investment.

Authors

Trisha Marsh Johnson1, Bernard Murphy21Veterinary & Environmental Technical Solutions, PC, 2 Jones-Hamilton Co.
Point of Contact:
Dr. Bernard Murphy, bmurphy@jones-hamilton.com

The information provided here was developed for the conference Mitigating Air Emissions From Animal Feeding Operations Conference held in May 2008. To obtain updates, readers are encouraged to contact the author.

Posted on

Diet Modification to Reduce Odors, Gas Emissions and Nutrient Excretions from Swine Operations

Can Changing Pig Diets Reduce Odor Emissions?

The pork industry has undergone a rapid change in the past two decades, with a decrease in farm numbers and an increase in farm size. These changes magnify the stress of the compatibility of pork production with neighbors in rural America. Concerns of the potential impact of the swine operation on water and air quality and health are also raised due to numerous compounds often produced from anaerobic degradation of animal manures, such as, sulfurous compounds, volatile fatty acids (VFAs), and ammonia (NH3). Since the pig is the point source of excreted nutrients resulting in gas and odor emissions, diet modification has the potential to reduce nutrient output and improve air quality.

Our hypothesis is that by utilizing a low nutrient excretion diet formulation and an alternative manure management strategy, the amount of nutrient output and gas/odor emissions will be reduced over the wean-finish period.

Activities

A total of 1, 920 pigs (initial BW = 5.29 kg) were used in a 2 x 2 factorial, wean-finish experiment to determine the effects of diet (control, CTL vs. low nutrient excretion, LNE) and manure management (6 mo. deep-pit, DP vs. monthly pull plug-recharge, PP) on growth performance, nutrient output, and air quality. Pigs were housed in a 12-room environmental building.

Pigs were split-sex and phase-fed to meet or exceed their nutrient requirements (NRC, 1998) at different stages of growth. The CTL and LNE diets were corn-soybean meal based and formulated to an equal Lysine:calorie. The LNE diet formulation had reduced CP and P, increased synthetic amino acids, phytase, non-sulfur trace mineral premix and added fat. Improvements in pig performance were observed over the wean-finish period.

Did Lysine Affect Performance or Odorous Emissions?

Pigs fed the LNE diets were 4.3 kg heavier (131.2 vs. 126.9 kg) at market, gain was increased by 0.03 kg/d (0.83 vs. 0.80 kg/d), feed intake was reduced by 0.16 kg/d (1.95 vs. 2.11 kg/d), and overall feed efficiency was increased by 11.6% (0.43 vs. 0.38) compared to CTL fed pigs (P<0.01). In addition, manure generation was reduced by 0.39 L/pig/d when the LNE diets were fed vs. the CTL diets (4.05 vs. 4.44 L/pig/d, P<0.008).

Excretion of total N, P, and K was reduced (P<0.001) by 27.5, 42.5, and 20.4%, respectively, from LNE fed pigs. Pigs fed the LNE diets had a 25.5, 23.8, 32.3, 18.5, 35.8, and 26.7% reduction (P<0.05) in manure acetate, iso-butyrate, iso-valerate, valerate, and total VFA production, respectively, compared to CTL fed pigs. Using the PP manure strategy reduced manure ammonium N and VFA production by 10.3 % (16.5 vs. 18.4 g/pig/d; P<0.002) and 20.5% (26.0 vs. 32.7 mM/pig/d; P<0.001), respectively, compared to DP strategy. Pigs fed LNE diets had a 13.6% (P<0.001) reduction in aerial NH3 emissions over the wean-finish period compared to pigs fed CTL diets. Aerial H2S and SO2 emissions and odor were not different (P>0.10) between dietary treatments.

Why is This Important?

Feeding LNE diet formulations are effective in reducing environmental impacts of pork production while maintaining growth performance. In addition, utilizing a monthly pull plug-recharge manure management strategy can improve air quality parameters, however can be more labor intensive.

For More Information

Contact us at jradclif@purdue.edu or (765)496-7718.

By Scott Radcliffe, Brian Richert, Danielle Sholly, Ken Foster, Brandon Hollas, Teng Lim, Jiqin Ni, Al Heber, Alan Sutton – Purdue University

This report was prepared for the 2008 annual meeting of the regional research committee, S-1032 “Animal Manure and Waste Utilization, Treatment and Nuisance Avoidance for a Sustainable Agriculture”. This report is not peer-reviewed and the author has sole responsibility for the content.

Proudly powered by WordPress